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Synthesis, Crystal Structure, EPR Spectra of Cu²⁺ doped catena-poly[[diaquabis(methylisonicotinate-N)cadmium(II)]-μ-(sulfato-O:O′)] Single Crystal

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dc.authorscopusid16068224200
dc.authorscopusid36937620300
dc.authorscopusid6506850653
dc.authorscopusid6603897211
dc.contributor.authorBozkurt, E.
dc.contributor.authorDöner, A.
dc.contributor.authorUçar, I.
dc.contributor.authorKarabulut, B.
dc.date.accessioned2020-06-21T14:41:19Z
dc.date.available2020-06-21T14:41:19Z
dc.date.issued2011
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Bozkurt] Esat, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Döner] Ahmet, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Uçar] İbrahim, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Karabulut] Bünyamin, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe [Cd(SO<inf>4</inf>)(C<inf>7</inf>H<inf>7</inf>NO<inf>2</inf>) <inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>]<inf>n</inf> complex has been synthesized and characterized by spectroscopic IR, EPR and X-ray diffraction technique. The compound crystallizes in space group P2<inf>1</inf>/c. The Cd(II) ion is octahedrally coordinated by two aqua, two methylisonicotinate and two sulfate ligands. The methylisonicotinate ligands are N-coordinated, while the sulfate ligands bridge the metal centers, forming the one-dimensional chain structure along the crystallographic [1 0 0] direction. The invidual chains are linked by O-H···O hydrogen bonds. The magnetic environments of Cu2+ doped [Cd(SO<inf>4</inf>)(C<inf>7</inf>H<inf>7</inf>NO <inf>2</inf>)<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>]<inf>n</inf> complex have been identified by EPR technique. The vibrational spectra of this compound was discussed. © 2010 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.cplett.2010.12.036
dc.identifier.endpage168en_US
dc.identifier.issn0009-2614
dc.identifier.scopus2-s2.0-78751641601
dc.identifier.scopusqualityQ2
dc.identifier.startpage163en_US
dc.identifier.urihttps://doi.org/10.1016/j.cplett.2010.12.036
dc.identifier.volume502en_US
dc.identifier.wosWOS:000286417800005
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.relation.journalChemical Physics Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSynthesis, Crystal Structure, EPR Spectra of Cu²⁺ doped catena-poly[[diaquabis(methylisonicotinate-N)cadmium(II)]-μ-(sulfato-O:O′)] Single Crystalen_US
dc.typeArticleen_US
dspace.entity.typePublication

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