Publication: EPR of Gamma Irradiation Induced Radicals in NaHCO3, CsHCO3 and Na2CO3
| dc.authorscopusid | 35555793900 | |
| dc.authorscopusid | 55909091300 | |
| dc.contributor.author | Köksal, F. | |
| dc.contributor.author | Köseoǧlu, R. | |
| dc.date.accessioned | 2020-06-21T15:50:10Z | |
| dc.date.available | 2020-06-21T15:50:10Z | |
| dc.date.issued | 2000 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Köksal] Fevzi, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Köseoǧlu] Rahmi, Department of Physics, Niğde Ömer Halisdemir University, Nigde, Nigde, Turkey | en_US |
| dc.description.abstract | In this study gamma irradiated NaHCO<inf>3</inf>, CsHCO<inf>3</inf> and Na<inf>2</inf>CO<inf>3</inf> were investigated at room temperature. The radicals induced by gamma irradiation in NaHCO<inf>3</inf> were found to be C(·)O<inf>3</inf>/-, HC(·)O<inf>3</inf> and C(·)O<inf>2</inf>/-; in CsHCO<inf>3</inf> the species were attributed to HC(·)O<inf>3</inf>; and in Na<inf>2</inf>CO<inf>3</inf> to C(·)O<inf>3</inf>/- and C(·)O<inf>2</inf>/- radicals. The hyperfine parameters for the hydrogen in HC(·)O<inf>3</inf>, and the 13C nucleus in C(·)<inf>2</inf>/- radical have been determined. The results were compared with literature data for similar compounds and the EPR properties of the C(·)<inf>2</inf>/- radical were discussed.; In this study gamma irradiated NaHCO<inf>3</inf>, CsHCO<inf>3</inf> and Na<inf>2</inf>CO<inf>3</inf> were investigated at room temperature. The radicals induced by gamma irradiation in NaHCO<inf>3</inf> were found to be C·O<inf>3</inf>-, HC·O<inf>3</inf> and C·O<inf>2</inf>-; in CsHCO<inf>3</inf> the species were attributed to HC·O<inf>3</inf>; and in Na<inf>2</inf>CO<inf>3</inf> to C·O<inf>3</inf>- and C·O<inf>2</inf>- radicals. The hyperfine parameters for the hydrogen in HC·O<inf>3</inf>, and the 13C nucleus in C·O<inf>2</inf>- radical have been determined. The results were compared with literature data for similar compounds and the EPR properties of the C·O<inf>2</inf>- radical were discussed. | en_US |
| dc.identifier.doi | 10.1016/S0969-806X(99)00299-6 | |
| dc.identifier.endpage | 61 | en_US |
| dc.identifier.issn | 1879-0895 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopus | 2-s2.0-0038193725 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 59 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/S0969-806X(99)00299-6 | |
| dc.identifier.volume | 57 | en_US |
| dc.identifier.wos | WOS:000084833400008 | |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Science Ltd | en_US |
| dc.relation.ispartof | Radiation Physics and Chemistry | en_US |
| dc.relation.journal | Radiation Physics and Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Caesium Bicarbonate | en_US |
| dc.subject | EPR | en_US |
| dc.subject | Gamma Irradiation | en_US |
| dc.subject | Sodium Bicarbonate | en_US |
| dc.subject | Sodium Carbonate | en_US |
| dc.title | EPR of Gamma Irradiation Induced Radicals in NaHCO3, CsHCO3 and Na2CO3 | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |