The First Bis(Orotato-N,O) Complex: Synthesis, Crystal Structure, Spectroscopic and Thermal Characterization of (CHAH)2[Cu(HOr-N,O)2(Cha)] · 2H2O (Cha = Cyclohexylamine and Hor = Orotate(2-))

Yeşilel, O.Z.; Paşaoĝlu, H.; Akdaǧ, K.; Büyuk̈güngör, O.

doi:10.1016/j.poly.2007.01.050

Publication:
The First Bis(Orotato-N,O) Complex: Synthesis, Crystal Structure, Spectroscopic and Thermal Characterization of (CHAH)2[Cu(HOr-N,O)2(Cha)] · 2H2O (Cha = Cyclohexylamine and Hor = Orotate(2-))

dc.authorscopusid	16403949600
dc.authorscopusid	6603689883
dc.authorscopusid	16678426700
dc.authorscopusid	36039473500
dc.contributor.author	Yeşilel, O.Z.
dc.contributor.author	Paşaoĝlu, H.
dc.contributor.author	Akdaǧ, K.
dc.contributor.author	Büyuk̈güngör, O.
dc.date.accessioned	2020-06-21T15:19:25Z
dc.date.available	2020-06-21T15:19:25Z
dc.date.issued	2007
dc.department	Ondokuz Mayıs Üniversitesi	en_US
dc.department-temp	[Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Paşaoĝlu] Hümeyra, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Akdaǧ] Kamber, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey	en_US
dc.description.abstract	The novel bis(cyclohexylaminium) cyclohexylaminebis(orotate-N,O)cuprate(II) dihydrate, (C<inf>6</inf>H<inf>15</inf>N)<inf>2</inf>[Cu(C<inf>5</inf>H<inf>2</inf>N<inf>2</inf>O<inf>4</inf>)<inf>2</inf>(C<inf>6</inf>H<inf>14</inf>N)] · 2H<inf>2</inf>O, has been prepared and characterized by elemental analysis, magnetic measurements, FT-IR and UV-Vis spectroscopy, thermal analysis and X-ray diffraction. The Cu(II) complex crystallizes in the monoclinic space group P2<inf>1</inf>/c. The copper atom in the five-coordinated (chaH)<inf>2</inf>[Cu(HOr-N,O)<inf>2</inf>(cha)] · 2H<inf>2</inf>O is chelated by a deprotonated pyrimidine nitrogen atom and carboxylate oxygen atom as a bis(bidentate) ligand and the cyclohexylamine ligand completes the square-pyramidal coordination. The thermal decomposition of the complex has been predicted by the help of thermal analysis (TG, DTG and DTA). © 2007 Elsevier Ltd. All rights reserved.	en_US
dc.identifier.doi	10.1016/j.poly.2007.01.050
dc.identifier.endpage	2766	en_US
dc.identifier.issn	0277-5387
dc.identifier.issue	12	en_US
dc.identifier.scopus	2-s2.0-34347254979
dc.identifier.scopusquality	Q2
dc.identifier.startpage	2761	en_US
dc.identifier.uri	https://doi.org/10.1016/j.poly.2007.01.050
dc.identifier.volume	26	en_US
dc.identifier.wos	WOS:000248633900049
dc.identifier.wosquality	Q2
dc.language.iso	en	en_US
dc.publisher	Elsevier Ltd	en_US
dc.relation.ispartof	Polyhedron	en_US
dc.relation.journal	Polyhedron	en_US
dc.relation.publicationcategory	Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı	en_US
dc.rights	info:eu-repo/semantics/closedAccess	en_US
dc.subject	Copper(II) Complex	en_US
dc.subject	Cyclohexylamine Complex	en_US
dc.subject	Orotate Complex	en_US
dc.subject	Thermal Decomposition	en_US
dc.title	The First Bis(Orotato-N,O) Complex: Synthesis, Crystal Structure, Spectroscopic and Thermal Characterization of (CHAH)2[Cu(HOr-N,O)2(Cha)] · 2H2O (Cha = Cyclohexylamine and Hor = Orotate(2-))	en_US
dc.type	Article	en_US
dspace.entity.type	Publication

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Publication: The First Bis(Orotato-N,O) Complex: Synthesis, Crystal Structure, Spectroscopic and Thermal Characterization of (CHAH)2[Cu(HOr-N,O)2(Cha)] · 2H2O (Cha = Cyclohexylamine and Hor = Orotate(2-))

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Publication:
The First Bis(Orotato-N,O) Complex: Synthesis, Crystal Structure, Spectroscopic and Thermal Characterization of (CHAH)2[Cu(HOr-N,O)2(Cha)] · 2H2O (Cha = Cyclohexylamine and Hor = Orotate(2-))