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Preparation and Crystallographic Characterization of Pd(II) Complexes Containing Imidobis(Diphenylthiophosphinato) Ligand

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dc.authorscopusid12786215700
dc.authorscopusid55988060100
dc.authorscopusid36039473500
dc.contributor.authorYanar, S.
dc.contributor.authorIrişli, S.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:18:55Z
dc.date.available2020-06-21T15:18:55Z
dc.date.issued2007
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yanar] Selmin, Department of Inorganic Chemistry, Ege Üniversitesi, Izmir, Turkey; [Irişli] Sevil, Department of Inorganic Chemistry, Ege Üniversitesi, Izmir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe reactions of PdCI<inf>2</inf>(L-L) [L-L = Ph<inf>2</inf>PCH<inf>2</inf>PPh<inf>2</inf>(dppm), Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>(dppe) and Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>(dppp)] with equivalent amount of (Ph<inf>2</inf>P(S)NHP(S)Ph<inf>2</inf>)(dppaS<inf>2</inf>) gave the complexes [Pd(L-L)(dppaS<inf>2</inf>-H)]ClO<inf>4</inf> [L-L = dppm (1), dppe (2), dppp (3)]. The different synthetic route was used for complex 2 by using of Pd(dppe)Cl<inf>2</inf> and K[N(PSPh<inf>2</inf>)<inf>2</inf>] as starting materials (2a). All of these complexes have been characterized 31P{1H} NMR, IR and elemental analyses. The complexes 2, 2a and 3 were crystallographically characterized. The coordination geometry around the Pd atoms in these complexes distorted square planar. Six membered dppaS<inf>2</inf>-H rings are twist boat conformations in three complexes. © 2007 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.poly.2007.05.007
dc.identifier.endpage4118en_US
dc.identifier.issn0277-5387
dc.identifier.issue15en_US
dc.identifier.scopus2-s2.0-34548286408
dc.identifier.scopusqualityQ2
dc.identifier.startpage4114en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2007.05.007
dc.identifier.volume26en_US
dc.identifier.wosWOS:000249905900011
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChalcogenide Ligandsen_US
dc.subjectDiphosphinesen_US
dc.subjectPalladium Complexesen_US
dc.subjectPhosphine Complexesen_US
dc.subjectPhosphinesen_US
dc.subjectX-Ray Crystal Structuresen_US
dc.titlePreparation and Crystallographic Characterization of Pd(II) Complexes Containing Imidobis(Diphenylthiophosphinato) Liganden_US
dc.typeArticleen_US
dspace.entity.typePublication

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