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Synthesis, Crystal Structure, Vibrational Spectra and Thermal Property of the Cyano-Bridged Hetero-Nuclear Polymeric Complex [Cd(pea)2Ni(μ-CN)4]n

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dc.authorscopusid49863490200
dc.authorscopusid16403949600
dc.authorscopusid35145306800
dc.authorscopusid36039473500
dc.contributor.authorKürkçüoǧlu, G.S.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorÇayli, Í.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:12:42Z
dc.date.available2020-06-21T15:12:42Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Çayli] Ílkay, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractThe cyano-bridged heterometallic complex, [Cd(pea)<inf>2</inf>Ni(μ-CN) <inf>4</inf>]<inf>n</inf>, (1), (pea = 2-phenylethylamine), has been synthesized and characterized by single crystal X-ray diffraction analysis, vibrational (FT-IR and Raman) spectroscopy, elemental and thermal analyses. The crystallographic analysis reveals that the crystal structure of the complex consists of a corrugated two dimensional network, in which the coordination environment of the Cd(II) 7 ion possesses a distorted octahedral geometry, whereas that of Ni(II) has a square planar geometry. The spectral features are consistent with pea coordination to the cadmium ion of the [Cd-Ni(μ-CN) <inf>4</inf>]<inf>n</inf>, layers as a monodentate ligand. © by Oldenbourg Wissenschaftsverlag, München.en_US
dc.identifier.doi10.1524/zkri.2009.1176
dc.identifier.endpage498en_US
dc.identifier.issn0044-2968
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-70449411737
dc.identifier.startpage493en_US
dc.identifier.urihttps://doi.org/10.1524/zkri.2009.1176
dc.identifier.volume224en_US
dc.identifier.wosWOS:000271327800004
dc.language.isoenen_US
dc.publisherWalter de Gruyter GmbHen_US
dc.relation.ispartofZeitschrift für Kristallographieen_US
dc.relation.journalZeitschrift Fur Kristallographieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSynthesis, Crystal Structure, Vibrational Spectra and Thermal Property of the Cyano-Bridged Hetero-Nuclear Polymeric Complex [Cd(pea)2Ni(μ-CN)4]nen_US
dc.typeArticleen_US
dspace.entity.typePublication

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