• Türkçe
    • English
  • English 
    • Türkçe
    • English
  • Login
View Item 
  •   DSpace Home
  • Araştırma Çıktıları | TR-Dizin | WoS | Scopus | PubMed
  • WoS İndeksli Yayınlar Koleksiyonu
  • View Item
  •   DSpace Home
  • Araştırma Çıktıları | TR-Dizin | WoS | Scopus | PubMed
  • WoS İndeksli Yayınlar Koleksiyonu
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Synthesis, Characterization and Crystal Structure of a Novel Three-Dimensional Supramolecular Framework Containing Ni center dot center dot center dot pi Interaction Heteronuclear Complex: {[Cu(4(5)-Meim)(4)][Ni(CN)(4)] center dot A H2O}(n)

Date

2009

Author

Kuerkcueoglu, Guenes Sueheyla
Yeşilel, Orkan Zafer
Kavlak, Ilkan
Kurtaran, Sema
Büyükgüngör, Orhan

Metadata

Show full item record

Abstract

The heteronuclear complex, {[Cu(4(5)-Meim)(4)][Ni(CN)(4)] center dot A H2O}(n) (1), (4(5)-Meim = 4(5)-methylimidazole) was synthesized and characterized by FT-IR spectroscopy, single crystal X-ray diffraction, thermal analysis and elemental analysis. The Cu(II) ion has a distorted square planar geometry, extended to (4 + 2) weak coordination by two nitrogen atoms of the cyano group. The coordination sphere around the Ni(II) ion should be described as a 4 + 2 geometry with the four cyano groups and the axial coordination site is located at the imidazole ring though a weak Ni center dot center dot center dot pi interaction. The coordination bond is much stronger than the Ni center dot center dot center dot pi interactions and it is expected that the formation of the coordination bond will affect more significantly the position of the absorption bands associated with the vibrations of the ligand. In addition, the out-of-plane modes of 4(5)-Meim are shifted to higher frequencies relative to free ligand. We propose that these shifts are indicative of the weak CHa (TM) a (TM) a (TM)pi and Nia (TM) a (TM) a (TM)pi interactions, according to the crystallographic and spectroscopic data.

Source

Journal of Inorganic and Organometallic Polymers and Materials

Volume

19

Issue

3

URI

https://doi.org/10.1007/s10904-009-9277-5
https://hdl.handle.net/20.500.12712/18469

Collections

  • Scopus İndeksli Yayınlar Koleksiyonu [14046]
  • WoS İndeksli Yayınlar Koleksiyonu [12971]

Related items

Showing items related by title, author, creator and subject.

  • Mixed ligand complexes of coumarilic acid/nicotinamide with transition metal complexes 

    Kose, Dursun Ali; Ozturk, Banu; Sahin, Onur; Büyükgüngör, Orhan (Springer, 2014)
    Coumarilate-nicotinamide complexes of Co-II and Zn-II were synthesized and investigated by elemental analysis, magnetic susceptibility, solid state UV-Vis, direct injection probe mass spectra, FTIR spectra, thermoanalytic ...
  • New copper(II) complexes including pyridine-2,5-dicarboxylic acid: synthesis, spectroscopic, thermal properties, crystal structure and how these complexes interact with purified PON 1 enzyme 

    Caglar, Sema; Dilek, Esra; Alisir, Sevim Hamamci; Caglar, Bulent (Taylor & Francis Ltd, 2016)
    We report the synthesis of two square-pyramidal copper(II) complexes, [Cu(2,5-pydc)(2-aepy)(H2O)]H2O, 1, and [Cu(2,5-pydc)(2-ampy)(H2O)]H2O, 2 (2-aepy=2-(aminoethyl)pyridine, 2-ampy=2-(aminomethyl)pyridine, 2,5-pydc=pyri ...
  • Synthesis and structural characterization of a new Schiff base macrocyclic ligand containing a piperazine head unit and its metal complexes. Crystal structure of the Co(II) complex 

    Keypour, Hassan; Rahpeyma, Nasibeh; Rezaeivala, Majid; Arzhangi, Parisa; Bayat, Mehdi; Valencia, Laura; Büyükgüngör, Orhan (Pergamon-Elsevier Science Ltd, 2013)
    A new macrocyclic Schiff base ligand, L, was synthesized by the condensation reaction of 1,4-bis(2-formylphenyl)piperazine and 1,4-diaminobutane in acetonitrile. The Schiff base ligand was characterized by elemental analysis, ...



DSpace software copyright © 2002-2015  DuraSpace
Contact Us | Send Feedback
Theme by 
@mire NV
 

 




| Policy | Guide | Contact |

DSpace@Ondokuz Mayıs

by OpenAIRE

Advanced Search

sherpa/romeo

Browse

All of DSpaceCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsTypeLanguageDepartmentCategoryPublisherAccess TypeInstitution AuthorThis CollectionBy Issue DateAuthorsTitlesSubjectsTypeLanguageDepartmentCategoryPublisherAccess TypeInstitution Author

My Account

LoginRegister

Statistics

View Google Analytics Statistics

DSpace software copyright © 2002-2015  DuraSpace
Contact Us | Send Feedback
Theme by 
@mire NV
 

 


|| Policy || Library || Ondokuz University || OAI-PMH ||

Ondokuz Mayıs University, Samsun, Turkey
If you find any errors in content, please contact:

Creative Commons License
Ondokuz University Institutional Repository is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 4.0 Unported License..

DSpace@Ondokuz Mayıs:


DSpace 6.2

tarafından İdeal DSpace hizmetleri çerçevesinde özelleştirilerek kurulmuştur.