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A Kinetic Study of Acid-Catalyzed Hydrolysis of Some Arylsulfonyl Phthalimides

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dc.authorscopusid6701793097
dc.authorscopusid26040988800
dc.contributor.authorKütük, H.
dc.contributor.authorOzturk, S.
dc.date.accessioned2020-06-21T15:12:35Z
dc.date.available2020-06-21T15:12:35Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kütük] Halil, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Ozturk] Seyhan, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe acid-catalyzed hydrolysis of arylsulfonyl phthalimides was studied in aqueous solutions of sulfuric, perchloric, and hydrochloric acid at 35.0 ± 0.1C. Analysis of the data by the excess acidity method and activation parameters, as well as substituent and solvent isotope effects, indicate hydrolysis by an A-2 mechanism at low acidity. At higher acidities, a changeover to an A-1 mechanism is observed.en_US
dc.identifier.doi10.1080/10426500802119655
dc.identifier.endpage340en_US
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-61449116986
dc.identifier.scopusqualityQ4
dc.identifier.startpage332en_US
dc.identifier.urihttps://doi.org/10.1080/10426500802119655
dc.identifier.volume184en_US
dc.identifier.wosWOS:000263093600007
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.journalPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcid-Catalyzed Hydrolysisen_US
dc.subjectArylsulfonyl Phthalimidesen_US
dc.subjectExcess Acidityen_US
dc.subjectMechanismen_US
dc.titleA Kinetic Study of Acid-Catalyzed Hydrolysis of Some Arylsulfonyl Phthalimidesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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