Publication: New Three-Dimensional (3,4)-Net Zincophosphites Templated by Linear Diammonium Cations: H3N(CH2)5NH3·Zn3(HPO3)4 and β-H3N(CH2)6NH3·Zn3(HPO3)4
| dc.authorscopusid | 16021922900 | |
| dc.authorscopusid | 15033124400 | |
| dc.authorscopusid | 58717985000 | |
| dc.authorscopusid | 36039473500 | |
| dc.contributor.author | Holtby, A.S. | |
| dc.contributor.author | Harrison, W.T.A. | |
| dc.contributor.author | Yilmaz, V.T. | |
| dc.contributor.author | Büyuk̈güngör, O. | |
| dc.date.accessioned | 2020-06-21T15:24:03Z | |
| dc.date.available | 2020-06-21T15:24:03Z | |
| dc.date.issued | 2007 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Holtby] Andrew S., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdom; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdom; [Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey | en_US |
| dc.description.abstract | The mild-condition syntheses, single-crystal structures and properties of H<inf>3</inf>N(CH<inf>2</inf>)<inf>5</inf>NH<inf>3</inf>·Zn<inf>3</inf>(HPO<inf>3</inf>)<inf>4</inf> and β-H<inf>3</inf>N(CH<inf>2</inf>)<inf>6</inf>NH<inf>3</inf>·Zn<inf>3</inf>(HPO<inf>3</inf>)<inf>4</inf> are reported. Both are constructed from (3,4)-nets of ZnO<inf>4</inf> tetrahedra and HPO<inf>3</inf> pyramids, sharing vertices to result in three-dimensional anionic open-frameworks. In both materials, the organic species interacts with the framework by way of N-H⋯O bonds. Crystal data: H<inf>3</inf>N(CH<inf>2</inf>)<inf>5</inf>NH<inf>3</inf>·Zn<inf>3</inf>(HPO<inf>3</inf>)<inf>4</inf>, M<inf>r</inf> = 620.22, orthorhombic, Pccn (No. 56), a = 9.5364 (9) Å, b = 21.8015 (19) Å, c = 9.1118 (7) Å, V = 1894.4 (3) Å3, Z = 4, R(F) = 0.044, wR(F2) = 0.111. β-H<inf>3</inf>N(CH<inf>2</inf>)<inf>6</inf>NH<inf>3</inf>·Zn<inf>3</inf>(HPO<inf>3</inf>)<inf>4</inf>, M<inf>r</inf> = 634.25, monoclinic, P2<inf>1</inf>/n (No. 14), a = 8.7627 (1) Å, b = 13.8117 (2) Å, c = 16.6187 (3) Å, β = 92.680 (1)°, V = 2009.12 (5) Å3, Z = 4, R(F) = 0.072, wR(F2) = 0.187. © 2006 Elsevier Masson SAS. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.solidstatesciences.2006.11.001 | |
| dc.identifier.endpage | 154 | en_US |
| dc.identifier.issn | 1293-2558 | |
| dc.identifier.issue | 2 | en_US |
| dc.identifier.scopus | 2-s2.0-33847264380 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 149 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.solidstatesciences.2006.11.001 | |
| dc.identifier.volume | 9 | en_US |
| dc.identifier.wos | WOS:000245212400004 | |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier | en_US |
| dc.relation.ispartof | Solid State Sciences | en_US |
| dc.relation.journal | Solid State Sciences | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Crystal Structure | en_US |
| dc.subject | Hydrothermal Synthesis | en_US |
| dc.subject | Zincophosphite | en_US |
| dc.title | New Three-Dimensional (3,4)-Net Zincophosphites Templated by Linear Diammonium Cations: H3N(CH2)5NH3·Zn3(HPO3)4 and β-H3N(CH2)6NH3·Zn3(HPO3)4 | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |