Publication:
Electron Paramagnetic Resonance of Cu2+ in Na3PO4·8H2O Single Crystal

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dc.authorscopusid35555793900
dc.authorscopusid6603897211
dc.authorscopusid55940997400
dc.contributor.authorKöksal, F.
dc.contributor.authorKarabulut, B.
dc.contributor.authorYerli, Y.
dc.date.accessioned2020-06-21T15:49:12Z
dc.date.available2020-06-21T15:49:12Z
dc.date.issued2001
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Köksal] Fevzi, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Karabulut] Bünyamin, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yerli] Yusuf, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe electron paramagnetic resonance spectra of Cu2+ in an Na<inf>3</inf>PO<inf>4</inf>·8H<inf>2</inf>O single crystal were studied at room temperature. The spectra indicate the presence of two magnetically inequivalent sites and monoclinic symmetry of the crystal. The principal values of the g and the hyperfine tensors were determined and were found to be in agreement with the literature values. It is proposed that the Cu2+ ions replace the Na+ ions, and the charge compensation is fulfilled by the charge of a nearby proton vacancy of the coordinating water molecules. The ground state wavefunction of the Cu2+ is thought to be an admixture of the 3d<inf>x2-y2</inf> and 3d<inf>z2</inf> orbitals and the admixtures of the two magnetically inequivalent sites were obtained. © 2001 Elsevier Science Ltd.en_US
dc.identifier.doi10.1016/S1466-6049(01)00017-4
dc.identifier.endpage416en_US
dc.identifier.issn1466-6049
dc.identifier.scopus2-s2.0-0034940608
dc.identifier.startpage413en_US
dc.identifier.urihttps://doi.org/10.1016/S1466-6049(01)00017-4
dc.identifier.urihttps://hdl.handle.net/20.500.12712/22172
dc.identifier.volume3en_US
dc.identifier.wosWOS:000169816800019
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofInternational Journal of Inorganic Materialsen_US
dc.relation.journalInternational Journal of Inorganic Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectDopingen_US
dc.subjectElectron Paramagnetic Resonanceen_US
dc.subjectInorganic Compoundsen_US
dc.subjectSpin-Hamiltonian Parametersen_US
dc.titleElectron Paramagnetic Resonance of Cu2+ in Na3PO4·8H2O Single Crystalen_US
dc.typeArticleen_US
dspace.entity.typePublication

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