Publication:
Formation of an Oxychloride Overlayer at a Bi(0001) Surface

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dc.contributor.authorAfsin, B
dc.contributor.authorRoberts, Mw
dc.date.accessioned2020-06-21T11:33:20Z
dc.date.available2020-06-21T11:33:20Z
dc.date.issued1994
dc.departmentOMÜen_US
dc.department-tempUNIV WALES COLL CARDIFF, SCH CHEM & APPL CHEM, CARDIFF CF1 3TB, S GLAM, WALES --en_US
dc.description.abstractA facile oxygen-induced chemisorptive replacement reaction occurs when a Bi(0001)-O overlayer is exposed to hydrogen chloride at 298K. The overlayer, which conforms to the stoichiometry BiOCl2, is stable in contrast to analogous chemistry observed earlier with a Pb(110) surface. Evidence for discrete localized states associated with Bi2+ or Bi3+ species is observed from shifts in the Bi(4f) binding energies while the charge distribution within the bismuth-chlorine bond is shown to be sensitive to the presence of oxygen adatoms within the oxy-chloride overlayer.en_US
dc.identifier.doi10.1080/00387019408002513
dc.identifier.endpage146en_US
dc.identifier.issn0038-7010
dc.identifier.issn1532-2289
dc.identifier.issue1en_US
dc.identifier.startpage139en_US
dc.identifier.urihttps://doi.org/10.1080/00387019408002513
dc.identifier.urihttps://hdl.handle.net/20.500.12712/9946
dc.identifier.volume27en_US
dc.identifier.wosWOS:A1994MT29700010
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.journalSpectroscopy Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectX-Ray Photoelectron Spectroscopyen_US
dc.subjectOxychlorideen_US
dc.subjectH-Abstractionen_US
dc.subjectFacile Chemisorptionen_US
dc.titleFormation of an Oxychloride Overlayer at a Bi(0001) Surfaceen_US
dc.typeArticleen_US
dspace.entity.typePublication

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