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Synthesis, Characterization and Catalytic Activity of Novel N-Heterocyclic Carbene-Palladium Complexes

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dc.contributor.authorDogan, Oznur
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorSahin, Onur
dc.contributor.authorBüyükgüngör, Orhan
dc.contributor.authorIDCetinkaya, Bekir/0000-0002-4551-8650
dc.contributor.authorIDSahin, Onur/0000-0003-3765-3235
dc.date.accessioned2020-06-21T15:07:49Z
dc.date.available2020-06-21T15:07:49Z
dc.date.issued2009
dc.departmentOMÜen_US
dc.department-temp[Dogan, Oznur -- Gurbuz, Nevin -- Ozdemir, Ismail] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey -- [Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey -- [Sahin, Onur -- Büyükgüngör, Orhan] Ondokuz Mayis Univ, Dept Phys, TR-55139 Samsun, Turkey --en_US
dc.description.abstractThe reaction of Pd(OAc)(2) with 1-(benzhydryl)-3-(alkyl) benzimidazolium salts 1a-d yields trans-bis[1-(benzhydryl)-3-(alkyl)benzimidazolin-2-ylidene]dibromopalladium(II) complexes (2a-d) which were characterized by elemental analysis, NMR spectroscopy and the molecular structures of 2b, and 2d were determined by X-ray crystallography. The catalytic activity of PdBr(2)bis(benzimidazolin-2- ylidene) complexes 2a-d was evaluated in the direct arylation reaction of benzothiazole with bromobenzene derivatives.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-CNRS (France)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-U/181 (106T716)]; Inonu University Research FundInonu University [2009/13]; Faculty of Arts and Sciences, Ondokuz Mayis University, TurkeyOndokuz Mayis University [F279]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)], Inonu University Research Fund (I.U.B.A.P: 2009/13) and the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased from grant no. F279 of the University Research Fund).en_US
dc.identifier.doi10.1039/b906497b
dc.identifier.endpage7093en_US
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.issue35en_US
dc.identifier.pmid20449152
dc.identifier.startpage7087en_US
dc.identifier.urihttps://doi.org/10.1039/b906497b
dc.identifier.urihttps://hdl.handle.net/20.500.12712/18887
dc.identifier.wosWOS:000269288700027
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.journalDalton Transactionsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSynthesis, Characterization and Catalytic Activity of Novel N-Heterocyclic Carbene-Palladium Complexesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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