Publication:
Two Fluorescent Silver(I)-Saccharinato Complexes of 2-Methylpyrazine and Pyrazine-2-Carboxamide with Ag⋯Ag Interactions

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dc.authorscopusid58717985000
dc.authorscopusid7801406100
dc.authorscopusid25027291500
dc.authorscopusid8600292400
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorSenel, E.
dc.contributor.authorGüney, E.
dc.contributor.authorKazak, C.
dc.date.accessioned2020-06-21T15:12:53Z
dc.date.available2020-06-21T15:12:53Z
dc.date.issued2008
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Senel] Evrim, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Güney] Emel, Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Kazak] Canan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractTwo new silver(I)-saccharinato (sac) complexes [Ag<inf>4</inf>(sac)<inf>4</inf>(mpyz)<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>] (1), and [Ag<inf>2</inf>(sac)<inf>2</inf>(pyzca)<inf>2</inf>] (2), (mpyz = 2-methylpyrazine, pyzca = pyrazine-2-carboxamide) have been synthesized and structurally characterized. Bridging of silver(I) centers by sac ligands results in argentophilic contacts of 3.192(1) Å for 1, and 3.168(2) Å for 2. These Ag⋯Ag interactions were discussed in terms of bond distances and angles around the silver(I) ion. Both complexes exhibit strong blue luminescence at room temperature in the solid state. © 2008 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.inoche.2008.08.014
dc.identifier.endpage1333en_US
dc.identifier.issn1387-7003
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-55049135525
dc.identifier.scopusqualityQ2
dc.identifier.startpage1330en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2008.08.014
dc.identifier.volume11en_US
dc.identifier.wosWOS:000261543100006
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.journalInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Methylpyrazineen_US
dc.subjectCrystal Structureen_US
dc.subjectFluorescenceen_US
dc.subjectPyrazine-2-Carboxamideen_US
dc.subjectSaccharinateen_US
dc.subjectSilver(I) Complexesen_US
dc.titleTwo Fluorescent Silver(I)-Saccharinato Complexes of 2-Methylpyrazine and Pyrazine-2-Carboxamide with Ag⋯Ag Interactionsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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