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A Novel Three Dimensional Organic-Inorganic Hybrid Based Porous Phase: Synthesis and Characterization of Reduced Oxovanadium Pyromellitate, [VIV2O2(H2O)2(C6H2(COO)4)]

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dc.authorscopusid55881082500
dc.authorscopusid14010024700
dc.authorscopusid7004490652
dc.authorscopusid36039473500
dc.contributor.authorÇevik, S.
dc.contributor.authorPoyraz, M.
dc.contributor.authorSarí, M.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:19:39Z
dc.date.available2020-06-21T15:19:39Z
dc.date.issued2007
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çevik] Sabri, Department of Chemistry, Afyon Kocatepe Üniversitesi, Afyonkarahisar, Afyonkarahisar, Turkey; [Poyraz] Mehmet, Department of Chemistry, Afyon Kocatepe Üniversitesi, Afyonkarahisar, Afyonkarahisar, Turkey; [Sarí] Musa, Department of Physical Education, Gazi Üniversitesi, Ankara, Ankara, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe hydrothermal reaction of a mixture of VOSO <inf>4</inf> • xH <inf>2</inf> O, 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid) and 0.1 M H <inf>2</inf> SO <inf>4</inf> for 72 h at 160 °C gives blue needle like crystals of [V IV <inf>2</inf> O <inf>2</inf> (H <inf>2</inf> O) <inf>2</inf> (C <inf>6</inf> H <inf>2</inf> (COO) <inf>4</inf> )] in 30% yield. The compound has a porous 3-D extended network structure having a rigid architecture which is held together by the multidentate functionalities of 1,2,4,5-benzenetetracarboxylate ligand. Crystal data for the compound: monoclinic space group C 2/c (No:15), a = 11.756(5) Å, b = 9.645(3) Å, c = 11.822(7) Å, β = 107.10(4)°, Z = 8. The compound constitutes the first example of a fully reduced oxovanadium based solid incorporating the organic ligand. This article consists of synthesis, crystal structure and characterization of [V IV <inf>2</inf> O <inf>2</inf> (H <inf>2</inf> O) <inf>2</inf> (C <inf>6</inf> H <inf>2</inf> (COO) <inf>4</inf> )]. © Springer Science+Business Media, LLC 2007.en_US
dc.identifier.doi10.1007/s10870-007-9203-z
dc.identifier.endpage502en_US
dc.identifier.issn1074-1542
dc.identifier.issn1572-8854
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-34347268097
dc.identifier.scopusqualityQ4
dc.identifier.startpage497en_US
dc.identifier.urihttps://doi.org/10.1007/s10870-007-9203-z
dc.identifier.volume37en_US
dc.identifier.wosWOS:000247414400011
dc.identifier.wosqualityQ4
dc.language.isoenen_US
dc.publisherSpringer New Yorken_US
dc.relation.ispartofJournal of Chemical Crystallographyen_US
dc.relation.journalJournal of Chemical Crystallographyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHydrothermal Synthesisen_US
dc.subjectOrganic-Inorganic Hybrid Compositesen_US
dc.subjectPyromellitateen_US
dc.subjectReduced Oxovanadiumen_US
dc.subjectStructure and Characterizationen_US
dc.subjectSynthesis and Designen_US
dc.titleA Novel Three Dimensional Organic-Inorganic Hybrid Based Porous Phase: Synthesis and Characterization of Reduced Oxovanadium Pyromellitate, [VIV2O2(H2O)2(C6H2(COO)4)]en_US
dc.title.alternativeV Iv 2 O 2 (H 2 O) 2 (C 6 H 2 (Coo) 4 )en_US
dc.typeArticleen_US
dspace.entity.typePublication

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