Publication:
Synthesis and Crystal Structure of Tetraquaorotatonickel(II) Monohydrate

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dc.authorscopusid8361848500
dc.authorscopusid36039473500
dc.authorscopusid8870164800
dc.authorscopusid35186645900
dc.contributor.authorSahin, O.
dc.contributor.authorBüyuk̈güngör, O.
dc.contributor.authorKöse, D.A.
dc.contributor.authorZümreǧlu-Karan, B.
dc.date.accessioned2020-06-21T09:24:44Z
dc.date.available2020-06-21T09:24:44Z
dc.date.issued2008
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Sahin] Onur, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Köse] Dursun Ali, Department of Chemistry, Hacettepe Üniversitesi, Ankara, Turkey; [Zümreǧlu-Karan] Birgül, Department of Chemistry, Hacettepe Üniversitesi, Ankara, Turkeyen_US
dc.description.abstractThe title compound, tetraquaorotatonickel(II) monohydrate, C<inf>5</inf>H<inf>12</inf>N<inf>2</inf>O<inf>9</inf>Ni, crystallizes in the monoclinic space group P1 with the following unit-cell parameters: a = 7.2282(4)Å, b = 8.2959(4)Å, c = 10.0611(5)Å, α = 80.115(4)°, β = 70.479(4)°, γ = 65.779(4)° and Z = 2. The NiII ion is coordinated by a deprotonated N atom and the carboxylate O atom of the orotate ligand and four aqua ligands in a distorted octahedral geometry. Intermolecular N-H·O and O-H·O hydrogen bonds produce R<inf>2</inf>2(8), R<inf>2</inf>2(12), R<inf>2</inf>2(16), R<inf>3</inf>2(8), R<inf>4</inf>3(8) and R<inf>4</inf>4(12) rings, which lead to a one-dimensional polymeric chains. An extensive three-dimensional network of N-H···O and O-H···O hydrogen bonds, π-π and N-H···π interactions are responsible for crystal stabilization. 2008 © The Japan Society for Analytical Chemistry.en_US
dc.identifier.doi10.2116/analscix.24.x211
dc.identifier.endpagex212en_US
dc.identifier.issn1348-2238
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-70649090990
dc.identifier.startpagex211en_US
dc.identifier.urihttps://doi.org/10.2116/analscix.24.x211
dc.identifier.volume24en_US
dc.language.isoenen_US
dc.publisherJapan Society for Analytical Chemistryen_US
dc.relation.ispartofAnalytical Sciences: X-ray Structure Analysis Onlineen_US
dc.relation.journalAnalytical Sciences: X-ray Structure Analysis Onlineen_US
dc.relation.publicationcategoryDiğeren_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleSynthesis and Crystal Structure of Tetraquaorotatonickel(II) Monohydrateen_US
dc.typeNoteen_US
dspace.entity.typePublication

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