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Synthesis, Characterization, Crystal Structures and Thermal and Fluorescence Studies of Dinuclear and Polymeric Silver(I) Complexes of 5,5-Diethylbarbiturate with 2,5-Dimethylpyrazine and Piperazine Involving Ag-Ag Interactions

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dc.authorscopusid32267686800
dc.authorscopusid55394789700
dc.authorscopusid58717985000
dc.authorscopusid36039473500
dc.authorscopusid15033124400
dc.contributor.authorSoyer, E.
dc.contributor.authorYilmaz, F.
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorBüyuk̈güngör, O.
dc.contributor.authorHarrison, W.T.A.
dc.date.accessioned2020-06-21T14:48:09Z
dc.date.available2020-06-21T14:48:09Z
dc.date.issued2010
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Soyer] Eda, Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Yilmaz] Fatih, Department of Chemistry, Recep Tayyip Erdogan University, Rize, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdomen_US
dc.description.abstractTwo silver(I) complexes, [Ag(dmpyz) <inf>2</inf>][Ag(barb) <inf>2</inf>] (1) and {[Ag(ppz)][Ag(barb) <inf>2</inf>]·H <inf>2</inf>O} <inf>n</inf> (2) (barb = 5,5-diethylbarbiturate, dmpyz = 2,5-dimethylpyrazine and ppz = piperazine), have been synthesized and characterized by elemental analyses, IR, thermal analysis (TG-DTA) and single-crystal X-ray diffraction. Complex 1 consists of [Ag(dmpyz) <inf>2</inf>] + and [Ag(barb) <inf>2</inf>] - ions in which the silver(I) ions are linearly coordinated by two dmpyz or two barb ligands. These two ions are connected by strong Ag-Ag interactions (Ag-Ag = 2.896 (1) Å). Complex 2 is a 1D coordination polymer in which the silver(I) ions are bridged by the ppz ligands in a linear fashion, leading to a zigzag chain of [Ag(ppz)] <inf>n</inf> +, which interacts with the [Ag(barb) <inf>2</inf>] - units by Ag-Ag interactions of 3.183 (1) Å. The 1D chains are further assembled to form 3D networks by strong N-H···O and OW-H···O hydrogen bonds. IR spectra and TG-DTA data are in agreement with the crystal structures. The fluorescent properties of 1 were also evaluated. © 2010 Springer Science+Business Media, LLC.en_US
dc.identifier.doi10.1007/s10904-010-9342-0
dc.identifier.endpage325en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-77952039437
dc.identifier.scopusqualityQ1
dc.identifier.startpage320en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-010-9342-0
dc.identifier.volume20en_US
dc.identifier.wosWOS:000277284600016
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.journalJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2,5-Dimethylpyrazineen_US
dc.subject5,5-Diethylbarbiturateen_US
dc.subjectAg-Ag Interactionsen_US
dc.subjectCoordination Polymeren_US
dc.subjectPiperazineen_US
dc.titleSynthesis, Characterization, Crystal Structures and Thermal and Fluorescence Studies of Dinuclear and Polymeric Silver(I) Complexes of 5,5-Diethylbarbiturate with 2,5-Dimethylpyrazine and Piperazine Involving Ag-Ag Interactionsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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