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Synthesis, Thermal, Spectroscopic and Structural Properties of di(aqua)bis(N,N′-dimethylethylenediamine-κ 2N,N′)copper(II) Acesulfamate

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dc.authorscopusid55159584400
dc.authorscopusid6602123654
dc.authorscopusid7003363958
dc.authorscopusid7006893434
dc.authorscopusid7005759139
dc.contributor.authorÍçbudak, H.
dc.contributor.authorUyanik, A.
dc.contributor.authorBulut, A.
dc.contributor.authorArici, C.
dc.contributor.authorÜlkü, D.
dc.date.accessioned2020-06-21T15:24:43Z
dc.date.available2020-06-21T15:24:43Z
dc.date.issued2007
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Íçbudak] Hasan, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Uyanik] Ahmet, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bulut] Ahmet, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Arici] Cengíz, Department of Physics Engineering, Hacettepe Üniversitesi, Ankara, Turkey; [Ülkü] Dínçer, Department of Physics Engineering, Hacettepe Üniversitesi, Ankara, Turkeyen_US
dc.description.abstractThe complex [Cu(C<inf>4</inf>H<inf>12</inf>N<inf>2</inf>) <inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>]2+ [(C<inf>4</inf>H <inf>4</inf>NO<inf>4</inf>S)-]<inf>2</inf>, which is the first structurally characterized complex with acesulfamate as the counter anion, has been synthesized and characterized by elemental analyses, magnetic and conductivity measurements, UV/vis, FT-IR and mass spectra. The thermal behaviour of the complexes was studied by simultaneous TG, DTG and DTA methods in a static air atmosphere. In the crystal structure, the copper cation, lying on a crystallographic centre of symmetry, adopts an elongated octahedral trans-[CuN<inf>4</inf>O<inf>2</inf>] coordination geometry, with long axial Cu-O(aqua) bond length and short equatorial Cu-N bonds, of 2.479(2), 2.035(2) and 2.051(2) Å, respectively. The coordinated water molecules together with the amine part of the dimethylethylenediamine molecule link the acesulfamate ions to the metal complex via intermolecular hydrogen bonds. © by Oldenbourg Wissenschaftsverlag.en_US
dc.identifier.doi10.1524/zkri.2007.222.8.432
dc.identifier.endpage436en_US
dc.identifier.issn0044-2968
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-34547575305
dc.identifier.startpage432en_US
dc.identifier.urihttps://doi.org/10.1524/zkri.2007.222.8.432
dc.identifier.volume222en_US
dc.identifier.wosWOS:000248548400008
dc.language.isoenen_US
dc.publisherWalter de Gruyter GmbHen_US
dc.relation.ispartofZeitschrift für Kristallographieen_US
dc.relation.journalZeitschrift Fur Kristallographieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcesulfamateen_US
dc.subjectMass Spectrometryen_US
dc.subjectN,N′-Dimethylethylenediamineen_US
dc.subjectSingle Crystal Structure Analysisen_US
dc.subjectThermal Analysisen_US
dc.subjectX-Ray Diffractionen_US
dc.titleSynthesis, Thermal, Spectroscopic and Structural Properties of di(aqua)bis(N,N′-dimethylethylenediamine-κ 2N,N′)copper(II) Acesulfamateen_US
dc.typeArticleen_US
dspace.entity.typePublication

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