Publication:
X-Ray and Spectroscopy Studies of Antisymbiotic Effect O-Coordination of the 4-Methoxy Benzoyl Methylene Triphenyl Phosphorane Ligand in Palladium(II) Complex

Simple item page
dc.authorscopusid24344289700
dc.authorscopusid36039473500
dc.contributor.authorKarami, K.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:06:41Z
dc.date.available2020-06-21T15:06:41Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Karami] Kazem, Department of Chemistry, Isfahan University of Technology, Isfahan, Isfahan, Iran; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractComplex [Pd(C<inf>6</inf>H<inf>4</inf>CH<inf>2</inf>NH<inf>2</inf>-k2-C,N)(Py)(OC (MeO-4-C<inf>6</inf>H<inf>4</inf>){double bond, long}CH-PPh<inf>3</inf>)]OTf (1) (OTf = CF3SO3) represents the example of an ylide O-bound to a Pd(II) center that is unusual for the classical soft metals. O-coordination of ylides and cisoid structure of complex was demonstrated by single-crystal X-ray analyses and spectroscopy. The IR and NMR data of the product (1), formed by the reaction of Pd(II) with the same ylide, are similar to those of O-bounded ylide. Analytical data indicate a 1:1 stoichiometry between the ylide and Pd (II) in the product (1). The molar conductivity of (1) Λ = 175 Ω-1 mol-1 cm2 is within the range for 1:1electrolytes. © 2008 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.ica.2008.12.013
dc.identifier.endpage2096en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-64449086121
dc.identifier.scopusqualityQ2
dc.identifier.startpage2093en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2008.12.013
dc.identifier.volume362en_US
dc.identifier.wosWOS:000265299200068
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier S.A.en_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.journalInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBenzylamineen_US
dc.subjectCrystal Structureen_US
dc.subjectPd(II) Complexesen_US
dc.subjectα-Ketostabilized Phosphorus Ylidesen_US
dc.titleX-Ray and Spectroscopy Studies of Antisymbiotic Effect O-Coordination of the 4-Methoxy Benzoyl Methylene Triphenyl Phosphorane Ligand in Palladium(II) Complexen_US
dc.typeArticleen_US
dspace.entity.typePublication

Files

Collections

Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu