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An EPR and Optical Absorption Study of Cu2+ Doped in Disodium Malonate Trihydrate Single Crystal

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dc.authorscopusid25652243200
dc.authorscopusid6603897211
dc.authorscopusid7005308678
dc.contributor.authorYarbaşi, Z.
dc.contributor.authorKarabulut, B.
dc.contributor.authorKarabulut, A.
dc.date.accessioned2020-06-21T15:07:06Z
dc.date.available2020-06-21T15:07:06Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yarbaşi] Zeynep, Department of Physics, Atatürk Üniversitesi, Erzurum, Erzurum, Turkey; [Karabulut] Bünyamin, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Karabulut] Abdulhalik, Department of Physics, Atatürk Üniversitesi, Erzurum, Erzurum, Turkeyen_US
dc.description.abstractSingle crystals and powder electron paramagnetic resonance (EPR) studies of Cu2+-doped disodium malonate trihydrate [C<inf>3</inf>H<inf>2</inf>O<inf>4</inf>Na<inf>2</inf>·3H<inf>2</inf>O] have been carried out at room temperature. The angular variation of the disodium malonate trihydrate single crystal have shown that two different Cu2+ complexes are located in different chemical environments, and each environment contains one magnetically inequivalent Cu2+ sites in distinct orientations occupying substitutional positions in the lattice and show very high angular dependence. The principal values of the g and the hyperfine tensors were determined and were found to be in agreement with the literature values. Crystal field around the Cu2+ ion is nearly rhombic. The optical absorption studies show two bands at 603 nm (16584 cm-1) and 890 nm (11236 cm-1) which confirm the rhombic symmetry. The crystals field parameters and than the wave function are determined. © 2008 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.saa.2008.10.004
dc.identifier.endpage368en_US
dc.identifier.issn1386-1425
dc.identifier.issue2en_US
dc.identifier.pmid19041279
dc.identifier.scopus2-s2.0-58149189911
dc.identifier.scopusqualityQ1
dc.identifier.startpage366en_US
dc.identifier.urihttps://doi.org/10.1016/j.saa.2008.10.004
dc.identifier.volume72en_US
dc.identifier.wosWOS:000263204200023
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopyen_US
dc.relation.journalSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCu2+en_US
dc.subjectDisodium Malonateen_US
dc.subjectEPRen_US
dc.subjectOptical Absorptionen_US
dc.subjectSpin-Hamiltonian Parametersen_US
dc.titleAn EPR and Optical Absorption Study of Cu2+ Doped in Disodium Malonate Trihydrate Single Crystalen_US
dc.typeArticleen_US
dspace.entity.typePublication

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