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The First Metal Complex of P-Nitrobenzoxasulfamate. Synthesis, Spectral and Structural Characterization of Triaquabis(p-Nitrobenzoxasulfamato)copper(II) Monohydrate

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dc.authorscopusid58717985000
dc.authorscopusid6603822664
dc.authorscopusid6602218261
dc.authorscopusid6701793097
dc.authorscopusid7801686683
dc.authorscopusid15033124400
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorAndaç, O.
dc.contributor.authorYazIcIlar, T.K.
dc.contributor.authorKütük, H.
dc.contributor.authorBekdemir, Y.
dc.contributor.authorHarrison, W.T.A.
dc.date.accessioned2020-06-21T15:48:48Z
dc.date.available2020-06-21T15:48:48Z
dc.date.issued2002
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Andaç] Ömer, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [YazIcIlar] Turan Kaya, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Kütük] Halil, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bekdemir] Yunus, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdomen_US
dc.description.abstractThe first Cu(II) complex of p-nitrobenzoxasulfamate (nbs) was characterized by elemental analysis, IR spectroscopy and single crystal X-ray spectrometry. Triaquabis(p- nitrobenzoxasulfamate)copper(II) monohydrate, [Cu(H<inf>2</inf>O)<inf>3</inf>(nbs)<inf>2</inf>·H<inf>2</inf>O, is mononuclear with square pyramidal geometry at the Cu(II) center. The Cu(II) ion is coordinated by two nbs ligands at the trans positions and three water molecules. The nbs ligand acts as a monodentate ligand through its negatively charged nitrogen atom and the Cu-N bond length is 1.9924(12) Å. The structure exhibits intermolecular hydrogen bonds involving the coordinated and lattice water molecules and the nitro and sulfonyl groups of the nbs ligands. © 2002 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.doi10.1016/S0022-2860(01)00933-4
dc.identifier.endpage76en_US
dc.identifier.issn0022-2860
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-0037042167
dc.identifier.scopusqualityQ1
dc.identifier.startpage71en_US
dc.identifier.urihttps://doi.org/10.1016/S0022-2860(01)00933-4
dc.identifier.volume608en_US
dc.identifier.wosWOS:000174630200010
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.journalJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCopper(II) Complexesen_US
dc.subjectCrystal Structureen_US
dc.subjectCyclic Sulfamateen_US
dc.subjectp-Nitrobenzoxasulfamateen_US
dc.titleThe First Metal Complex of P-Nitrobenzoxasulfamate. Synthesis, Spectral and Structural Characterization of Triaquabis(p-Nitrobenzoxasulfamato)copper(II) Monohydrateen_US
dc.typeArticleen_US
dspace.entity.typePublication

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