Publication:
Synthesis, X-Ray Structures, and Catalytic Activities of (κ2-C,N) Bearing Imidazol-2

Simple item page
dc.authorscopusid11439933100
dc.authorscopusid26635321400
dc.authorscopusid8398877200
dc.authorscopusid56054780100
dc.authorscopusid7006471258
dc.contributor.authorEmin Günay, M.
dc.contributor.authorGümüşada, R.
dc.contributor.authorÖzdemir, Nutullah
dc.contributor.authorDinçer, M.
dc.contributor.authorÇetinkaya, B.
dc.date.accessioned2020-06-21T15:06:21Z
dc.date.available2020-06-21T15:06:21Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Emin Günay] Muhammet, Department of Chemistry, Aydin Adnan Menderes University, Aydin, Efeler, Turkey; [Gümüşada] Rukiye, Department of Chemistry, Aydin Adnan Menderes University, Aydin, Efeler, Turkey; [Özdemir] Namık, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Dinçer] Muharrem, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Çetinkaya] Bekir, Department of Chemistry, Ege Üniversitesi, Izmir, Turkeyen_US
dc.description.abstractQuaternisation of methylimidazole (1) by methyl substituted benzyl bromides afforded imidazolium salts (2) which were converted to (κ2-C,N)-palladacycles bearing imidazol-2-ylidenes 6 or 7, by either in situ deprotonation or via Ag-NHC intermediate (3), using the bridged palladacycles 4 or 5, respectively. The palladacycles 6 and 7 were characterized by elemental analysis; NMR spectroscopy and the molecular structure of 6c and 7c were determined by X-ray crystallography. The complexes 6 and 7 display high activity in Suzuki-Miyaura coupling of a range of aryl bromides. © 2009 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2009.03.034
dc.identifier.endpage2349en_US
dc.identifier.issue15en_US
dc.identifier.scopus2-s2.0-66149102052
dc.identifier.startpage2343en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2009.03.034
dc.identifier.urihttps://hdl.handle.net/20.500.12712/18580
dc.identifier.volume694en_US
dc.identifier.wosWOS:000266638700008
dc.language.isoenen_US
dc.publisherElsevier Science SAen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.journalJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectImidazol-2-Ylidenesen_US
dc.subjectN-Heterocyclic Carbeneen_US
dc.subjectPalladacyclesen_US
dc.subjectSuzuki-Miyaura Couplingen_US
dc.titleSynthesis, X-Ray Structures, and Catalytic Activities of (κ2-C,N) Bearing Imidazol-2en_US
dc.typeArticleen_US
dspace.entity.typePublication

Files

Collections

Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu