Publication:
Theoretical and Experimental Studies of the Molecular Orbital Bonding Coefficients for Cu2+ Ion in Cesium Hydrogen Oxalate Single Crystals

Simple item page
dc.authorscopusid35074170300
dc.authorscopusid6603897211
dc.contributor.authorKalfaoǧlu, E.
dc.contributor.authorKarabulut, B.
dc.date.accessioned2020-06-21T13:40:06Z
dc.date.available2020-06-21T13:40:06Z
dc.date.issued2016
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kalfaoǧlu] Emel, Ministry of National Education, Duzce, Turkey; [Karabulut] Bünyamin, Department of Computer Engineering, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractElectron paramagnetic resonance (EPR) and optical absorption spectra of Cu2+ ions in cesium hydrogen oxalate single crystals have been investigated at room temperature. The spin-Hamiltonian parameters (g and A), have been determined. Crystalline field around the Cu2+ ion is almost axially symmetric. The results show a single paramagnetic site which confirms the triclinic crystal symmetry. Molecular orbital bonding coefficients are studied from the EPR and optical data. Theoretical octahedral field parameter and the tetragonal field parameters have been evaluated from the superposition model. Using these parameters, various bonding parameters are analyzed and the nature of bonding in the complex is discussed. The theoretical results are supported by experimental results. © 2016 AIP Publishing LLC.en_US
dc.identifier.doi10.1063/1.4944148
dc.identifier.isbn9780735446496
dc.identifier.isbn9780735452794
dc.identifier.isbn9780735451889
dc.identifier.isbn9780735450301
dc.identifier.isbn9780735441088
dc.identifier.isbn9780735403598
dc.identifier.isbn9780735444577
dc.identifier.isbn9780735443594
dc.identifier.isbn9780735448001
dc.identifier.isbn9780735416437
dc.identifier.issn1551-7616
dc.identifier.scopus2-s2.0-84984559366
dc.identifier.scopusqualityQ4
dc.identifier.urihttps://doi.org/10.1063/1.4944148
dc.identifier.volume1722en_US
dc.identifier.wosWOS:000375923300029
dc.language.isoenen_US
dc.publisherAmerican Institute of Physics Inc. subs@aip.orgen_US
dc.relation.ispartofAIP Conference Proceedingsen_US
dc.relation.ispartofseriesAIP Conference Proceedings
dc.relation.journal9Th International Physics Conference of the Balkan Physical Union (Bpu-9)en_US
dc.relation.publicationcategoryKonferans Öğesi - Uluslararası - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCesium Hydrogen Oxalateen_US
dc.subjectEPRen_US
dc.subjectMolecular Orbital Bonding Coefficientsen_US
dc.subjectOptical Spectraen_US
dc.subjectSuperposition Modelen_US
dc.titleTheoretical and Experimental Studies of the Molecular Orbital Bonding Coefficients for Cu2+ Ion in Cesium Hydrogen Oxalate Single Crystalsen_US
dc.typeConference Objecten_US
dspace.entity.typePublication

Files

Collections

Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu