Publication: A Three-Dimensional Silver(I) Coordination Polymer Involving a New Bridging Mode of Saccharinate
| dc.authorscopusid | 25027291500 | |
| dc.authorscopusid | 58717985000 | |
| dc.authorscopusid | 36039473500 | |
| dc.contributor.author | Güney, E. | |
| dc.contributor.author | Yilmaz, V.T. | |
| dc.contributor.author | Büyuk̈güngör, O. | |
| dc.date.accessioned | 2020-06-21T14:48:53Z | |
| dc.date.available | 2020-06-21T14:48:53Z | |
| dc.date.issued | 2010 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Güney] Emel, Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey | en_US |
| dc.description.abstract | A three-dimensional silver(I)-saccharinato (sac) coordination polymer [Ag<inf>2</inf>(μ-sac)<inf>2</inf>]<inf>n</inf> has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by the imino N and carbonyl O atoms of two sac ligands, leading to a dimer [Ag<inf>2</inf>(μ-sac)<inf>2</inf>] with a very short Ag-Ag contact of 2.8622(6) Å. The dimeric units are linked by unique Ag-C<inf>sac</inf> (η1) bonds into two-dimensional ladder-like layers, which are further assembled into a three-dimensional network by weak Ag⋯O(sulphonyl) and π(sac)⋯π(sac) interactions. Complex 1 is the first example of a polymeric network involving the η1 Ag-C bonds. In addition to the new coordination mode of sac, the IR spectrum and thermal properties of the complex were discussed. © 2010 Elsevier B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.inoche.2010.02.005 | |
| dc.identifier.endpage | 567 | en_US |
| dc.identifier.issn | 1387-7003 | |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.scopus | 2-s2.0-77949541612 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 563 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.inoche.2010.02.005 | |
| dc.identifier.volume | 13 | en_US |
| dc.identifier.wos | WOS:000276751000029 | |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier | en_US |
| dc.relation.ispartof | Inorganic Chemistry Communications | en_US |
| dc.relation.journal | Inorganic Chemistry Communications | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Ag⋯Ag Interaction | en_US |
| dc.subject | Ag-C Bond | en_US |
| dc.subject | Coordination Polymer | en_US |
| dc.subject | Saccharinate | en_US |
| dc.subject | Silver(I) | en_US |
| dc.title | A Three-Dimensional Silver(I) Coordination Polymer Involving a New Bridging Mode of Saccharinate | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |