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A Mononuclear, Mixed (Salicylato) (Nicotinamide) Complex of Zn(II) with Penta- and Hexa-Coordination Sites: A Novel Framework Structure

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dc.authorscopusid8870164800
dc.authorscopusid6701739413
dc.authorscopusid8361848500
dc.authorscopusid36039473500
dc.contributor.authorKöse, D.A.
dc.contributor.authorAy, A.N.
dc.contributor.authorSahin, O.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:18:35Z
dc.date.available2020-06-21T14:18:35Z
dc.date.issued2012
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Köse] Dursun Ali, Department of Chemistry, Hitit University, Corum, Corum, Turkey; [Ay] Ahmet Nedim, Department of Chemistry, Hacettepe Üniversitesi, Ankara, Turkey; [Sahin] Onur, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe title compound, diaqua(bissalicylato-jO) (bisnicotinamide-ΚN) zinc(II)][bis(triaqua (monosalicylato-jO) (mononicotinamide-ΚN)zinc(II) salicylate, includes three Zn(II) ions, four nicotinamide ligands, six salicylate ligands and eight coordinated aqua ligands in the asymmetric unit in complex structure. The geometry around one of the Zn(II) ions is a slightly distorted octahedron, of which the equatorial plane is formed by two carboxylate oxygens and two aqua oxygens, while the axial positions are occupied by two pyridyl nitrogen atoms. The other Zn(II) ions adopt fivefold coordinations with one carboxylate oxygen atom from salicylate ligand, one N atom from nicotinamide ligand and three oxygen atoms from aqua ligands. In addition, there are two salicylate anions in the unit cell that are not coordinated. They provide charge balance as counter-ions in the complex framework. © Iranian Chemical Society 2012.en_US
dc.identifier.doi10.1007/s13738-012-0072-9
dc.identifier.endpage597en_US
dc.identifier.issn1735-2428
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-84870903098
dc.identifier.scopusqualityQ2
dc.identifier.startpage591en_US
dc.identifier.urihttps://doi.org/10.1007/s13738-012-0072-9
dc.identifier.volume9en_US
dc.identifier.wosWOS:000306438400020
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of the Iranian Chemical Societyen_US
dc.relation.journalJournal of the Iranian Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHexa-Coordinated Zn(II)en_US
dc.subjectMixed-Ligand Complexesen_US
dc.subjectNicotinamide Complexesen_US
dc.subjectPenta-Coordinated Zn(II)en_US
dc.subjectSalicylic Acid Complexesen_US
dc.subjectZn(II) Complexesen_US
dc.titleA Mononuclear, Mixed (Salicylato) (Nicotinamide) Complex of Zn(II) with Penta- and Hexa-Coordination Sites: A Novel Framework Structureen_US
dc.typeArticleen_US
dspace.entity.typePublication

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