Publication:
The Synthesis, Characterization and Structural Analysis of a Co(III) Complex of 1,10-Phenanthroline and Perfluorosebacic Acid, [Co(hl)(phen)2(H2O)]L·H2O

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dc.authorscopusid6602109294
dc.authorscopusid36039473500
dc.authorscopusid7004432241
dc.contributor.authorKani, I.
dc.contributor.authorBüyuk̈güngör, O.
dc.contributor.authorYílmaz, F.
dc.date.accessioned2020-06-21T09:23:21Z
dc.date.available2020-06-21T09:23:21Z
dc.date.issued2006
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kani] Ibrahim, Department of Chemistry, Anadolu Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yílmaz] Filiz, Department of Chemistry, Anadolu Üniversitesi, Eskisehir, Eskisehir, Turkeyen_US
dc.description.abstractThe hexacoordinated mononuclear Co(III) complex 1, [Co(HL)(phen) <inf>2</inf>(H<inf>2</inf>O)]L·H<inf>2</inf>O, with the mixed ligands (H<inf>2</inf>L = HO<inf>2</inf>C(CF<inf>2</inf>)<inf>8</inf>CO<inf>2</inf>H and 1,10-phenantroline) has been synthesized and characterized by elemental analysis, IR and UV/vis spectroscopy, magnetic susceptibility, TG analysis and X-ray diffraction techniques. The Co(III) atom is coordinated asymmetrically by two bidentate 1,10 phenanthroline ligands, one hydrogencarboxylate ligand, (O<inf>2</inf>C(CF<inf>2</inf>)<inf>8</inf>CO<inf>2</inf>H)-, and one water molecule. In the crystal structure, there are also dicarboxylate anions and one water molecule attached through hydrogen bonds. Intermolecular π-π interactions between the adjacent phenanthroline ligands also support the packing of the components. © 2006 Verlag der Zeitschrift für Naturforschung.en_US
dc.identifier.doi10.1515/znb-2006-1002
dc.identifier.endpage1204en_US
dc.identifier.issn0932-0776
dc.identifier.issn1865-7117
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-33750951062
dc.identifier.scopusqualityQ3
dc.identifier.startpage1198en_US
dc.identifier.urihttps://doi.org/10.1515/znb-2006-1002
dc.identifier.volume61en_US
dc.identifier.wosqualityQ4
dc.language.isoenen_US
dc.publisherVerlag der Zeitschrift für Naturforschungen_US
dc.relation.ispartofZeitschrift Für Naturforschung Section B-A Journal of Chemical Sciencesen_US
dc.relation.journalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject1,10-Phenanthrolineen_US
dc.subjectCobalt(III) Complexen_US
dc.subjectHydrogen Bondingen_US
dc.subjectPerfluorosebacic Aciden_US
dc.subjectπ-π Interactionsen_US
dc.titleThe Synthesis, Characterization and Structural Analysis of a Co(III) Complex of 1,10-Phenanthroline and Perfluorosebacic Acid, [Co(hl)(phen)2(H2O)]L·H2Oen_US
dc.typeArticleen_US
dspace.entity.typePublication

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