Publication: Bis(pyridine-2,6 O, O ′)cobalt(II) and -Copper(II) Disaccharinate Dihydrate: Three-Dimensional Structures With Extensive Hydrogen Bonds and Aromatic Π-Π Interactions
| dc.authorscopusid | 6603822664 | |
| dc.authorscopusid | 6603070940 | |
| dc.authorscopusid | 6603007969 | |
| dc.authorscopusid | 58717985000 | |
| dc.authorscopusid | 15033124400 | |
| dc.contributor.author | Andaç, O. | |
| dc.contributor.author | Guney, S. | |
| dc.contributor.author | Topcu, Y. | |
| dc.contributor.author | Yilmaz, V.T. | |
| dc.contributor.author | Harrison, W.T.A. | |
| dc.date.accessioned | 2020-06-21T15:48:54Z | |
| dc.date.available | 2020-06-21T15:48:54Z | |
| dc.date.issued | 2002 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Andaç] Ömer, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Guney] Serkan, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Topcu] Yildiray, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey | en_US |
| dc.description.abstract | Bis(pyridine-2,6-dimethanol-N, O, O ′)cobalt(II) disaccharinate dihydrate, [Co(C<inf>7</inf>H<inf>9</inf>NO<inf>2</inf>)<inf>2</inf>](C<inf>7</inf>H<inf>4</inf>NO<inf>3</inf>S)<inf>2</inf>·2H<inf>2</inf>O, (I), and bis(pyridine-2,6-dimethanol-N, O, O ′)copper(II) disaccharinate dihydrate, [Cu(C<inf>7</inf>H<inf>9</inf>NO<inf>2</inf>)<inf>2</inf>](C<inf>7</inf>H<inf>4</inf>NO<inf>3</inf>S)<inf>2</inf>·2H<inf>2</inf>O, (II), collectively [M(dmpy)<inf>2</inf>](sac)<inf>2</inf>·2H<inf>2</inf>O (where M is CoII or CuII, sac is the saccharinate anion and dmpy is pyridine-2,6-dimethanol), are isostructural. The [M(dmpy)<inf>2</inf>]2+ cations exhibit distorted octahedral geometry in which the two neutral dmpy species act as tripodal N, O, O ′-tridentate ligands. The crystal packing is determined by hydrogen bonding, as well as by weak pyridine-saccharinate π-π-stacking interactions. | en_US |
| dc.identifier.doi | 10.1107/S0108270101018807 | |
| dc.identifier.endpage | m20 | en_US |
| dc.identifier.issn | 0108-2701 | |
| dc.identifier.issn | 1600-5759 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.pmid | 11781459 | |
| dc.identifier.scopus | 2-s2.0-0036303129 | |
| dc.identifier.startpage | m17 | en_US |
| dc.identifier.uri | https://doi.org/10.1107/S0108270101018807 | |
| dc.identifier.volume | 58 | en_US |
| dc.identifier.wos | WOS:000173143300015 | |
| dc.language.iso | en | en_US |
| dc.publisher | Blackwell Munksgaard | en_US |
| dc.relation.ispartof | Acta Crystallographica Section C: Crystal Structure Communications | en_US |
| dc.relation.journal | Acta Crystallographica Section C-Crystal Structure Communications | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Bis(pyridine-2,6 O, O ′)cobalt(II) and -Copper(II) Disaccharinate Dihydrate: Three-Dimensional Structures With Extensive Hydrogen Bonds and Aromatic Π-Π Interactions | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |