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Synthesis, Characterization, and Hydrogen Storage Capacities of Polymeric Squaric Acid Complexes Containing 1-Vinylimidazole

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dc.authorscopusid56182186600
dc.authorscopusid6603822664
dc.authorscopusid57188995258
dc.contributor.authorYilmaz, H.
dc.contributor.authorAndaç, O.
dc.contributor.authorGördük, S.
dc.date.accessioned2020-06-21T13:18:18Z
dc.date.available2020-06-21T13:18:18Z
dc.date.issued2017
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Hakan, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Andaç] Ömer, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Gördük] Semih, Department of Chemistry, Yıldız Teknik Üniversitesi, Istanbul, Turkeyen_US
dc.description.abstractIn this work, three new polymeric coordination complexes were synthesized using squaric acid and 1-vinylimidazole. The structures of the coordination polymers, formed with Co(II), Zn(II), and Cd(II) ions, were characterized by elemental analysis, infrared spectroscopy (IR), thermal analysis (Thermogravimetry, TG; Derivative Thermogravimetry, DTG; Differential Scanning Calorimetry, DSC), magnetic susceptibility, X-ray powder diffraction, and X-ray single crystal techniques. The X-ray single crystal method showed that the squarato ligand behaves as bis(monodentate) via the oxygen atoms in μ<inf>1,3</inf>-mode and 1-vinylimidazole coordinates to the metal ion via the ring nitrogen atom as monodentate in the complexes. The central ions in the complexes obtained as single crystal exhibited slightly distorted octahedral geometries. The surface areas and hydrogen storage capacities of the synthesized complexes were also examined. © 2017 Elsevier Ltden_US
dc.identifier.doi10.1016/j.poly.2017.05.014
dc.identifier.endpage23en_US
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85019552752
dc.identifier.scopusqualityQ2
dc.identifier.startpage16en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2017.05.014
dc.identifier.volume133en_US
dc.identifier.wosWOS:000405537200003
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPOLYHEDRONen_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1-Vinylimidazoleen_US
dc.subjectCoordination Polymeren_US
dc.subjectHydrogen Storageen_US
dc.subjectSquaric Aciden_US
dc.subjectSurface Areaen_US
dc.titleSynthesis, Characterization, and Hydrogen Storage Capacities of Polymeric Squaric Acid Complexes Containing 1-Vinylimidazoleen_US
dc.typeArticleen_US
dspace.entity.typePublication

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