Publication:
EPR of Cu2+ and VO2+ in a Cobalt Saccharin Complex, [Co(sac)2(H2O)4]·2H2O, Single Crystals

dc.authorscopusid55940997400
dc.authorscopusid35555793900
dc.authorscopusid56251081500
dc.contributor.authorYerli, Y.
dc.contributor.authorKöksal, F.
dc.contributor.authorKaradaǧ, A.
dc.date.accessioned2020-06-21T15:43:59Z
dc.date.available2020-06-21T15:43:59Z
dc.date.issued2003
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yerli] Yusuf, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Köksal] Fevzi, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Karadaǧ] Ahmet, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractCu2+ and VO2+ doped single crystals of [Co(sac) <inf>2</inf>(H<inf>2</inf>O)<inf>4</inf>]·2H<inf>2</inf>O (Cosacaqua) complex were investigated using EPR technique at ambient temperature. Detailed investigation of the EPR spectra indicated that the Cu2+ and VO 2+ substitute the Co2+. Two sites were observed for Cu2+ and VO2+. But each site of V4+ corresponds two different orientations of VO2+. The principal values of the g and the hyperfine tensors were obtained. The spectra indicate that the ground state for Cu2+ is mainly 3d<inf>x2-y2</inf>. The covalent bonding parameters for Cu2+ and VO2+ and Fermi contact terms were obtained. © 2003 Éditions scientifiques et médicales Elsevier SAS. All rights reserved.en_US
dc.identifier.doi10.1016/S1293-2558(03)00186-9
dc.identifier.endpage1323en_US
dc.identifier.issn1293-2558
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-0141460410
dc.identifier.scopusqualityQ2
dc.identifier.startpage1319en_US
dc.identifier.urihttps://doi.org/10.1016/S1293-2558(03)00186-9
dc.identifier.volume5en_US
dc.identifier.wosWOS:000185680500018
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherElsevier Masson SASen_US
dc.relation.ispartofSolid State Sciencesen_US
dc.relation.journalSolid State Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCobalt Saccharinen_US
dc.subjectCu2+en_US
dc.subjectDopingen_US
dc.subjectEPRen_US
dc.subjectVO2+en_US
dc.titleEPR of Cu2+ and VO2+ in a Cobalt Saccharin Complex, [Co(sac)2(H2O)4]·2H2O, Single Crystalsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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