Publication: Bis(Saccharinato)nickel Complexes With 2-Aminomethyl and -Ethylpyridines. Syntheses, Crystal Structures, Spectral and Thermal Analyses of Trans-[Ni(sac and Trans-Ni(sac
| dc.authorscopusid | 58717985000 | |
| dc.authorscopusid | 7005505517 | |
| dc.authorscopusid | 15033124400 | |
| dc.contributor.author | Yilmaz, V.T. | |
| dc.contributor.author | Caglar, S. | |
| dc.contributor.author | Harrison, W.T.A. | |
| dc.date.accessioned | 2020-06-21T15:38:34Z | |
| dc.date.available | 2020-06-21T15:38:34Z | |
| dc.date.issued | 2004 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Caglar] Sema, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdom | en_US |
| dc.description.abstract | The trans-bis(saccharinato)nickel(II) complexes with 2-aminomethylpyridine (ampy) and 2-aminoethylpyridine (aepy) have been prepared and characterized by elemental analyses, i.r., u.v.-vis., magnetic measurements and single crystal X-ray diffraction. Both structures consist of discrete molecules of the title complexes, in which the nickel(II) ion lies on an inversion centre and is octahedrally coordinated by two bidentate (N,N′) ampy or aepy ligands and two anionic sac ligands, occupying trans positions. The most interesting feature of the complexes is the coordination of sac. In [Ni(sac)<inf>2</inf>(ampy) <inf>2</inf>], sac is N-bonded, whereas it is O-coordinated in [Ni(sac) <inf>2</inf>(aepy)<inf>2</inf>]. The i.r. spectra and thermal behaviour of both complexes are discussed in detail. | en_US |
| dc.identifier.doi | 10.1023/B:TMCH.0000037511.10613.7a | |
| dc.identifier.endpage | 482 | en_US |
| dc.identifier.issn | 0340-4285 | |
| dc.identifier.issue | 5 | en_US |
| dc.identifier.scopus | 2-s2.0-4143141254 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 477 | en_US |
| dc.identifier.uri | https://doi.org/10.1023/B:TMCH.0000037511.10613.7a | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/21410 | |
| dc.identifier.volume | 29 | en_US |
| dc.identifier.wos | WOS:000223206200003 | |
| dc.identifier.wosquality | Q3 | |
| dc.language.iso | en | en_US |
| dc.publisher | Kluwer Academic Publishing | en_US |
| dc.relation.ispartof | Transition Metal Chemistry | en_US |
| dc.relation.journal | Transition Metal Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Bis(Saccharinato)nickel Complexes With 2-Aminomethyl and -Ethylpyridines. Syntheses, Crystal Structures, Spectral and Thermal Analyses of Trans-[Ni(sac and Trans-Ni(sac | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |