Publication: Cis-Diaquabis[2-(Hydroxymethyl)Pyridine]Nickel(II) Dichloride
| dc.authorscopusid | 6603157555 | |
| dc.authorscopusid | 58717985000 | |
| dc.authorscopusid | 7003491332 | |
| dc.contributor.author | Hamamci, S. | |
| dc.contributor.author | Yilmaz, V.T. | |
| dc.contributor.author | Thöne, C. | |
| dc.date.accessioned | 2020-06-21T15:43:24Z | |
| dc.date.available | 2020-06-21T15:43:24Z | |
| dc.date.issued | 2004 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Hamamci] Sevim, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Thöne] Carsten, Inst. F. Anorganische und Analyt. C., Technische Universität Braunschweig, Braunschweig, Niedersachsen, Germany | en_US |
| dc.description.abstract | The title complex, [Ni(mpy)<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>]Cl <inf>2</inf> [mpy is 2-(hydroxy-methyl)pyridine, C<inf>6</inf>H<inf>7</inf>NO], consists of two chloride anions and an [Ni(mpy)<inf>2</inf>(H<inf>2</inf>O) <inf>2</inf>]2+ cation, in which the NiII ion lies on a twofold axis and exhibits octahedral geometry, coordinated by two neutral mpy ligands and two water molecules. Mpy acts as an N,O-bidentate ligand, giving rise to a five-membered chelate ring. The Ni-N<inf>mpy,</inf> Ni-O<inf>mpy</inf> and Ni-O<inf>water</inf> bond distances are 2.0629 (8), 2.0573 (7) and 2.0490 (7) Å, respectively. The H atoms of the water molecules and the hydroxy group of mpy form O-H⋯Cl hydrogen bonds, resulting in a three-dimensional network. ©2004 International Union of Crystallography Printed in Great Britain - all rights reserved. | en_US |
| dc.identifier.doi | 10.1107/S1600536803026862 | |
| dc.identifier.endpage | m8 | en_US |
| dc.identifier.issn | 1600-5368 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopus | 2-s2.0-18444362412 | |
| dc.identifier.startpage | m6 | en_US |
| dc.identifier.uri | https://doi.org/10.1107/S1600536803026862 | |
| dc.identifier.volume | 60 | en_US |
| dc.identifier.wos | WOS:000187552200006 | |
| dc.language.iso | en | en_US |
| dc.publisher | Blackwell Munksgaard | en_US |
| dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online | en_US |
| dc.relation.journal | Acta Crystallographica Section E-Structure Reports Online | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Cis-Diaquabis[2-(Hydroxymethyl)Pyridine]Nickel(II) Dichloride | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |