Publication: Three Copper(II) Complexes of Thiophene-2,5 Acid with Dissimilar Ligands: Synthesis, IR and UV-Vis Spectra, Thermal Properties and Structural Characterizations
| dc.authorscopusid | 16403949600 | |
| dc.authorscopusid | 34167881800 | |
| dc.authorscopusid | 36039473500 | |
| dc.contributor.author | Yeşilel, O.Z. | |
| dc.contributor.author | Ilker, I. | |
| dc.contributor.author | Büyuk̈güngör, O. | |
| dc.date.accessioned | 2020-06-21T14:54:39Z | |
| dc.date.available | 2020-06-21T14:54:39Z | |
| dc.date.issued | 2009 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Ilker] Inci, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey | en_US |
| dc.description.abstract | Three thiophene-2,5-dicarboxylic acid (H<inf>2</inf>tdc) complexes of copper(II) with 2-aminomethylpyridine (ampy), {[Cu<inf>2</inf>(μ-tdc)<inf>2</inf>(ampy)<inf>2</inf>]·2DMF}<inf>n</inf> (1), ethylenediamine (en), trans-[Cu(H<inf>2</inf>O)<inf>2</inf>(en)<inf>2</inf>](tdc) (2) and 4-methylimidazole (4-meim), trans-[Cu(H<inf>2</inf>O)<inf>2</inf>(4-meim)<inf>4</inf>](tdc)·4H<inf>2</inf>O (3) have been synthesized and characterized by spectral (IR, UV-Vis), thermal analyses and X-ray diffraction techniques. In 1, thiophene-2,5-dicarboxylate acts as a bridging bis(bidentate) ligand through four carboxylate oxygen atoms forming a 1-D zigzag polymeric chain, whereas in 2 and 3 the tdc dianion behaves as a counter ion. In all cases, the Cu(II) centers have an octahedral coordination geometry. Three-dimensional frameworks are constructed though hydrogen bonding and/or C-H···π interactions in the three complexes. © 2009 Elsevier Ltd. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.poly.2009.06.044 | |
| dc.identifier.endpage | 3016 | en_US |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.issue | 14 | en_US |
| dc.identifier.scopus | 2-s2.0-69549103271 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 3010 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.poly.2009.06.044 | |
| dc.identifier.volume | 28 | en_US |
| dc.identifier.wos | WOS:000271358700027 | |
| dc.identifier.wosquality | Q2 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd | en_US |
| dc.relation.ispartof | Polyhedron | en_US |
| dc.relation.journal | Polyhedron | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | 2-Aminomethylpyridine Complex | en_US |
| dc.subject | 4-Methylimidazole Complex | en_US |
| dc.subject | Copper Complexes | en_US |
| dc.subject | Ethylenediamine Complex | en_US |
| dc.subject | Thiophene-2,5-Dicarboxylic Acid Complexes | en_US |
| dc.title | Three Copper(II) Complexes of Thiophene-2,5 Acid with Dissimilar Ligands: Synthesis, IR and UV-Vis Spectra, Thermal Properties and Structural Characterizations | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |