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Heteroleptic Ruthenium(II) Complexes of 2-(2 a Study of Catalytic Efficiency Towards Transfer Hydrogenation of Acetophenone

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dc.authorscopusid13805114500
dc.authorscopusid56418687900
dc.authorscopusid8398877200
dc.contributor.authorDayan, O.
dc.contributor.authorDemirmen, S.
dc.contributor.authorÖzdemir, Nutullah
dc.date.accessioned2020-06-21T13:51:03Z
dc.date.available2020-06-21T13:51:03Z
dc.date.issued2015
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Dayan] Osman, Department of Chemistry, Çanakkale Onsekiz Mart Üniversitesi, Canakkale, Canakkale, Turkey; [Demirmen] Selin, Department of Chemistry, Çanakkale Onsekiz Mart Üniversitesi, Canakkale, Canakkale, Turkey; [Özdemir] Namık, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractSix ruthenium(II) complexes ([RuCl<inf>2</inf>(p-cymene)(L1-6)], SD1-6, (L1-6: bidentate pyridyl-benzimidazole ligands)) were synthesized from [RuCl<inf>2</inf>(p-cymene)]<inf>2</inf> dimer and bidentate pyridyl-benzimidazole ligands. The compounds were characterized by elemental analysis, IR, UV-Vis, NMR and X-ray diffraction. The synthesized Ru(II) complexes (SD1-6) were tested as catalysts for the catalytic transfer hydrogenation (CTH) of acetophenone to secondary alcohols in the presence of KOH using 2-propanol as a hydrogen source at 82 °C. All complexes were active catalysts for TH of acetophenone with good yields under mild conditions (after 15 min, yields of up to 91%). © 2014 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.poly.2014.10.012
dc.identifier.endpage932en_US
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84910656825
dc.identifier.scopusqualityQ2
dc.identifier.startpage926en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2014.10.012
dc.identifier.volume85en_US
dc.identifier.wosWOS:000347582900119
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcetophenoneen_US
dc.subjectBenzimidazolesen_US
dc.subjectPyridinesen_US
dc.subjectRu(II) Complexesen_US
dc.subjectTransfer Hydrogenationen_US
dc.titleHeteroleptic Ruthenium(II) Complexes of 2-(2 a Study of Catalytic Efficiency Towards Transfer Hydrogenation of Acetophenoneen_US
dc.typeArticleen_US
dspace.entity.typePublication

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