Publication:
Synthesis, Crystal Structure, Spectroscopic and Thermal Properties of trans-[Ni(sac)(2)(aeppz)(2)] [sac =accharinate and aeppz N-(2-aminoethyl)piperazine]

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dc.authorscopusid6603070940
dc.authorscopusid58717985000
dc.authorscopusid15033124400
dc.contributor.authorGuney, S.
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorHarrison, W.T.A.
dc.date.accessioned2020-06-21T15:29:49Z
dc.date.available2020-06-21T15:29:49Z
dc.date.issued2005
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Guney] Serkan, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdomen_US
dc.description.abstractA nickel(II) complex of saccharinate (sac) with N-(2-aminoethyl)piperazine (aeppz), trans-[Ni(sac)<inf>2</inf>(aeppz)<inf>2</inf>], has been prepared and characterized by elemental analyses, IR, UV-vis, magnetic measurements and single crystal X-ray diffraction. The compound crystallizes in space group P1 (No. 2). The nickel(II) ion sits on an inversion centre and is octahedrally coordinated by two neutral aeppz and two anionic sac ligands. The aeppz ligand is bidentate (N,N′) chelating, while sac is O-coordinated through the carbonyl O atom. The IR spectrum of [Ni(sac)<inf>2</inf>(aeppz)<inf>2</inf>] displays typical absorption bands of bidentate aeppz and O-bonded sac ligands. Under atmospheric conditions, [Ni(sac)<inf>2</inf>(aeppz)<inf>2</inf>] is thermally stable up to 220°C, but at higher temperatures, loses two aeppz ligands between 220 and 317°C and two sac ligands in the temperature range 320-528°C, giving NiO as end product. © 2005 Taylor & Francis.en_US
dc.identifier.doi10.1080/00958970500229857
dc.identifier.endpage1674en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue18en_US
dc.identifier.scopus2-s2.0-29044449712
dc.identifier.scopusqualityQ3
dc.identifier.startpage1667en_US
dc.identifier.urihttps://doi.org/10.1080/00958970500229857
dc.identifier.urihttps://hdl.handle.net/20.500.12712/20833
dc.identifier.volume58en_US
dc.identifier.wosWOS:000233904800004
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.relation.journalJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectN-(2-Aminoethyl)Piperazineen_US
dc.subjectNickel(II) Complexen_US
dc.subjectSaccharinateen_US
dc.titleSynthesis, Crystal Structure, Spectroscopic and Thermal Properties of trans-[Ni(sac)(2)(aeppz)(2)] [sac =accharinate and aeppz N-(2-aminoethyl)piperazine]en_US
dc.title.alternativeNi(Sac)2en_US
dc.typeArticleen_US
dspace.entity.typePublication

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