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Kinetics and Mechanisms of the Acid-Catalyzed Hydrolyses of N-(4-Substitued-arylsulf inyl)phthalimides

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dc.authorscopusid6701793097
dc.authorscopusid7801686683
dc.authorscopusid6506171344
dc.contributor.authorKütük, H.
dc.contributor.authorBekdemir, Y.
dc.contributor.authorSoydas, Y.
dc.date.accessioned2020-06-21T15:49:18Z
dc.date.available2020-06-21T15:49:18Z
dc.date.issued2001
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kütük] Halil, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bekdemir] Yunus, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Soydas] Yasemin, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe acid-catalyzed hydrolyses of N-(4-substituted-arylsulfinyl)phthalimides were studied in aqueous solutions of perchloric and sulfuric acids at 50.0 ± 0.1 and of hydrochloric acid at 40.0 ± 0.1°C. Analysis of the data by the Cox-Yates excess acidity method and substituent, temperature and solvent isotope effects indicate hydrolysis by an A2 mechanism at low acidity. At higher acidities a changeover to an A1 mechanism is observed. Copyright © 2001 John Wiley & Sons, Ltd.en_US
dc.identifier.doi10.1002/poc.353
dc.identifier.endpage228en_US
dc.identifier.issn0894-3230
dc.identifier.issn1099-1395
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-0035310433
dc.identifier.scopusqualityQ3
dc.identifier.startpage224en_US
dc.identifier.urihttps://doi.org/10.1002/poc.353
dc.identifier.volume14en_US
dc.identifier.wosWOS:000167763800006
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherJohn Wiley & Sons Ltden_US
dc.relation.ispartofJournal of Physical Organic Chemistryen_US
dc.relation.journalJournal of Physical Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcid Catalysisen_US
dc.subjectExcess Acidityen_US
dc.subjectHydrolysisen_US
dc.subjectMechanismen_US
dc.subjectN-(4-Substituted-Arylsulfinyl)Phthalimidesen_US
dc.titleKinetics and Mechanisms of the Acid-Catalyzed Hydrolyses of N-(4-Substitued-arylsulf inyl)phthalimidesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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