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One- and Two-Dimensional Cadmium(II) Tetracyanonickelate(II) Coordination Polymers with Imidazole and 2-Methylimidazole Ligands

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dc.authorscopusid49863490200
dc.authorscopusid16403949600
dc.authorscopusid35145306800
dc.authorscopusid36039473500
dc.contributor.authorKürkçüoǧlu, G.S.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorÇayli, I.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:40:04Z
dc.date.available2020-06-21T14:40:04Z
dc.date.issued2011
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Çayli] Ílkay, Graduate School of Sciences, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractTwo novel cyano-bridged heteropolynuclear complexes, [Cd(im) <inf>4</inf>Ni(μ-CN) <inf>2</inf>(CN) <inf>2</inf>] <inf>n</inf> (1) and [Cd(mim) <inf>2</inf>Ni(μ-CN) <inf>4</inf>] <inf>n</inf> (2) (im: imidazole and mim: 2-methylimidazole), have been synthesized and characterized. In 1, the trans-directed cyanide ligands of [Ni(CN) <inf>4</inf>] 2- anions link two [Cd(im) <inf>4</inf>] 2+ units, whereas in 2, all the cyanide groups take part in bonding with two adjacent [Cd(mim) <inf>2</inf>] 2+ units, resulting 1D and 2D coordination polymers, respectively. The coordination environment of the Cd(II) ion described as distorted octahedral geometry, whereas around the Ni(II) centre had square planar geometry in both complexes. The crystals packing of 1 and 2 were a composite of hydrogen bonding, π···π and C-H···Ni interactions. © 2011 Springer Science+Business Media, LLC.en_US
dc.identifier.doi10.1007/s10904-010-9454-6
dc.identifier.endpage315en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-79957444327
dc.identifier.scopusqualityQ1
dc.identifier.startpage306en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-010-9454-6
dc.identifier.volume21en_US
dc.identifier.wosWOS:000290801600013
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.journalJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Methylimidazole Complexen_US
dc.subjectCoordination Polymersen_US
dc.subjectHeteronuclear Complexesen_US
dc.subjectImidazole Complexen_US
dc.subjectInfrared and Raman Spectraen_US
dc.subjectTetracyanonickelate(II) Complexesen_US
dc.titleOne- and Two-Dimensional Cadmium(II) Tetracyanonickelate(II) Coordination Polymers with Imidazole and 2-Methylimidazole Ligandsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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