Publication:
Silver, Palladium and Rhodium Complexes of Acenaphthylene-Anullated N-Heterocyclic Carbene Ligands: A Comparative Study

Simple item page
dc.authorscopusid6603574712
dc.authorscopusid8361848500
dc.authorscopusid36039473500
dc.authorscopusid7006471258
dc.contributor.authorTürkmen, H.
dc.contributor.authorSahin, O.
dc.contributor.authorBüyuk̈güngör, O.
dc.contributor.authorÇetinkaya, B.
dc.date.accessioned2020-06-21T15:24:44Z
dc.date.available2020-06-21T15:24:44Z
dc.date.issued2006
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Türkmen] Hayati, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Sahin] Onur, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Çetinkaya] Bekir, Department of Chemistry, Ege Üniversitesi, Izmir, Turkeyen_US
dc.description.abstractThe newly prepared carbene precursor 1,3-dimesitylacenaphtho[1,2-d] imidazolinium chloride, (NHC-H)Cl, 3, could be readily converted into the NHC-silver(I) complex, 4, which is an efficient carbene transfer agent and has been used to synthesise thione 5, trans-[PdCl<inf>2</inf>(NHC)<inf>2</inf>], 6 and [RhCl(NHC)(COD)], 7. All compounds synthesised were characterised by elemental analysis, NMR spectroscopy and the molecular structures of the thione 5 and complex 7 were determined by X-ray crystallography. Complex 7 was converted into cis-[RhCl(NHC)(CO)<inf>2</inf>] and the electron donating properties and trans influence of the NHC ligand were compared with nonanullated counterparts. The catalytic activity in the Heck reaction of 6 and the in situ formed palladium complex was evaluated. The activity of the in situ formed complexes for the Heck coupling of alkenes was high. © Wiley-VCH Verlag GmbH & Co. KGaA, 2006.en_US
dc.identifier.doi10.1002/ejic.200600545
dc.identifier.endpage4921en_US
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.issue23en_US
dc.identifier.scopus2-s2.0-33845605876
dc.identifier.scopusqualityQ2
dc.identifier.startpage4915en_US
dc.identifier.urihttps://doi.org/10.1002/ejic.200600545
dc.identifier.wosWOS:000243077400026
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherWiley-VCH Verlagen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.relation.journalEuropean Journal of Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectC-C Couplingen_US
dc.subjectN-Heterocyclic Carbenesen_US
dc.subjectPalladium Complexesen_US
dc.subjectRhodium Complexesen_US
dc.subjectSilver Complexesen_US
dc.subjectThionesen_US
dc.titleSilver, Palladium and Rhodium Complexes of Acenaphthylene-Anullated N-Heterocyclic Carbene Ligands: A Comparative Studyen_US
dc.typeArticleen_US
dspace.entity.typePublication

Files

Collections

Scopus İndeksli Yayınlar Koleksiyonu
Makale Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu