Publication:
Mono- and Binuclear Copper(II) Complexes of Saccharin With 2-Pyridinepropanol Synthesis, Spectral, and Thermal and Structural Characterization

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dc.authorscopusid58717985000
dc.authorscopusid6504575432
dc.authorscopusid6603822664
dc.authorscopusid7003491332
dc.authorscopusid15033124400
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorHamamei, S.
dc.contributor.authorAndaç, O.
dc.contributor.authorThöne, C.
dc.contributor.authorHarrison, W.T.A.
dc.date.accessioned2020-06-21T15:43:59Z
dc.date.available2020-06-21T15:43:59Z
dc.date.issued2003
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Hamamei] Sevim, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Andaç] Ömer, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Thöne] Carsten, Inst. Anorg. Analystische Chemie, Technische Universität Braunschweig, Braunschweig, Niedersachsen, Germany; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdomen_US
dc.description.abstractMono- and binuclear copper(II) saccharinate (sac) complexes containing 2-pyridinepropanol (pypr) have been prepared and characterized by elemental analyses, i.r., u.v.-vis., magnetic measurements and single crystal X-ray diffraction. The copper(II) ion in trans-[Cu(pypr)<inf>2</inf>(sac)<inf>2</inf>] has -1 site symmetry and is octahedrally coordinated by two bidentate neutral pypr (N, O) and two sac (O) ligands. The binuclear copper(II) complex, [Cu<inf>2</inf>(μ-pypr)<inf>2</inf>(sac)<inf>2</inf>], is built up around a centre of symmetry and contains two strongly distorted square planar coordinated copper(II) ions bridged by two alkoxo groups of the deprotonated pypr ligand, which also coordinates to the copper(II) ions through its nitrogen. In contrast to the mononuclear complex, the sac ligands in the binuclear complex is N-coordinated. The binuclear complex exhibits diamagnetic behaviour. The i.r. spectra and thermal decompositions of both complexes are described.en_US
dc.identifier.doi10.1023/A:1025437507627
dc.identifier.endpage681en_US
dc.identifier.issn0340-4285
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-0141853349
dc.identifier.scopusqualityQ3
dc.identifier.startpage676en_US
dc.identifier.urihttps://doi.org/10.1023/A:1025437507627
dc.identifier.volume28en_US
dc.identifier.wosWOS:000184990400013
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.journalTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleMono- and Binuclear Copper(II) Complexes of Saccharin With 2-Pyridinepropanol Synthesis, Spectral, and Thermal and Structural Characterizationen_US
dc.typeArticleen_US
dspace.entity.typePublication

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