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Structural, Spectroscopic and Voltammetric Studies of bis(Acetazolamido)bis(Aquo)bis(Nicotinamide)Copper(II)

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dc.authorscopusid55360958000
dc.authorscopusid7003363958
dc.authorscopusid6603689883
dc.authorscopusid6602801811
dc.authorscopusid36039473500
dc.contributor.authorÖztürk, F.
dc.contributor.authorBulut, A.
dc.contributor.authorPaşaoĝlu, H.
dc.contributor.authorBulut, I.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:17:27Z
dc.date.available2020-06-21T14:17:27Z
dc.date.issued2012
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Öztürk] Filiz, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Bulut] Ahmet, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Paşaoĝlu] Hümeyra, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Bulut] Iclal, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractPolymeric copper(II) complex, [Cu(Hacm)<inf>2</inf>(na)<inf>2</inf>(H <inf>2</inf>O)<inf>2</inf>] [H<inf>2</inf>acm; acetazolamide, na; nicotinamide] was synthesized and characterized by spectroscopic (IR; infrared spectroscopy, EPR; electron paramagnetic resonance), structural (XRD) and voltammetric structural (CV) methods. The copper(II) compound crystallizes in the triclinic space group P1̄, Z = 1, with the unit-cell dimensions: a = 7.672 (5) Å, b = 8.681 (5) Å, c = 11.938 (5) Å, α = 90.807 (7)°, β = 98.616 (5)° and γ = 110.647 (5)°. The Cu(II) ion has a distorted octahedral coordination geometry. The crystal packing of the complex is stabilized by intermolecular O-H...O and N-H...O hydrogen bonds. The powder EPR spectrum of copper(II) complex have indicate that the paramagnetic center is in a tetragonal symmetry with the Cu2+ ion having a distorted octahedral geometry. The vibrational investigation has been carried out on the basis of some characteristic IR bands of acetazolamide and nicotinamide molecules. © 2012 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.saa.2012.05.036
dc.identifier.endpage30en_US
dc.identifier.issn1386-1425
dc.identifier.pmid22750334
dc.identifier.scopus2-s2.0-84866413838
dc.identifier.scopusqualityQ1
dc.identifier.startpage24en_US
dc.identifier.urihttps://doi.org/10.1016/j.saa.2012.05.036
dc.identifier.urihttps://hdl.handle.net/20.500.12712/16280
dc.identifier.volume97en_US
dc.identifier.wosWOS:000310395800004
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.journalSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcetazolamideen_US
dc.subjectCu(II)en_US
dc.subjectCyclic Voltammetryen_US
dc.subjectEPRen_US
dc.subjectIren_US
dc.subjectX-Ray Crystal Structureen_US
dc.titleStructural, Spectroscopic and Voltammetric Studies of bis(Acetazolamido)bis(Aquo)bis(Nicotinamide)Copper(II)en_US
dc.typeArticleen_US
dspace.entity.typePublication

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