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Molecular Structures and Spectroscopic Studies of Cationic Metal-Methylisonicotinate Complexes with Saccharinate Counterions

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dc.authorscopusid16068224200
dc.authorscopusid55220288900
dc.authorscopusid6506850653
dc.authorscopusid6603897211
dc.contributor.authorBozkurt, E.
dc.contributor.authorAyaz, H.
dc.contributor.authorUçar, I.
dc.contributor.authorKarabulut, B.
dc.date.accessioned2020-06-21T14:18:39Z
dc.date.available2020-06-21T14:18:39Z
dc.date.issued2012
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Bozkurt] Esat, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Ayaz] Hüseyin, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Uçar] İbrahim, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Karabulut] Bünyamin, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe crystal structures of [Co(methylisonicotinate)<inf>2</inf>(H <inf>2</inf>O)<inf>4</inf>](saccharinate)<inf>2</inf> and [Ni(methylisonicotinate)<inf>2</inf>(H<inf>2</inf>O)<inf>4</inf>](saccharinate) <inf>2</inf> complexes have been synthesized and characterized by spectroscopic, EPR and X-ray diffraction techniques. The XRD data have indicated that both the Co(II) and Ni(II) ions lie on an inversion center, having distorted octahedral coordination through four aqua ligands composing the basal plane and two trans nitrogen atoms from the monodentate methylisonicotinate ligands occupying the axial sites. The EPR spectra of these complexes have been studied in the temperature range between 113 and 300 K in three mutually perpendicular planes. The EPR spectral results were discussed and compared in relation with the other compounds containing saccharinate and methylisonicotinate complexes. © 2012 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.ica.2012.04.008
dc.identifier.endpage7en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84861169641
dc.identifier.scopusqualityQ2
dc.identifier.startpage1en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2012.04.008
dc.identifier.volume390en_US
dc.identifier.wosWOS:000305811000001
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier S.A.en_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.journalInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectEPRen_US
dc.subjectX-Ray Diffractionen_US
dc.titleMolecular Structures and Spectroscopic Studies of Cationic Metal-Methylisonicotinate Complexes with Saccharinate Counterionsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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