Publication: Crystal Structure and Hirshfeld Surface Analysis of 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(Azanylyl-Idene)]bis-(Methanylyl-Idene)}bis-[4-(Trifluoro-Methoxy)phenol]copper(II) Hydro-Quinone Hemisolvate
| dc.authorscopusid | 57194716371 | |
| dc.authorscopusid | 57205390951 | |
| dc.authorscopusid | 57201620841 | |
| dc.authorscopusid | 8338164600 | |
| dc.authorscopusid | 6701698973 | |
| dc.contributor.author | Kansız, S. | |
| dc.contributor.author | Meral, S. | |
| dc.contributor.author | Dege, N. | |
| dc.contributor.author | Aǧar, A.A. | |
| dc.contributor.author | Fritsky, I.O. | |
| dc.date.accessioned | 2020-06-21T12:25:46Z | |
| dc.date.available | 2020-06-21T12:25:46Z | |
| dc.date.issued | 2019 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Kansız] Sevgi, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Meral] Seher, Vocational School, Sinop Üniversitesi, Sinop, Turkey; [Dege] Necmi, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Aǧar] Ayşen Alaman, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Fritsky] Igor Olegovich, Department of Chemistry, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine | en_US |
| dc.description.abstract | In the title complex, [Cu(C<inf>18</inf>H<inf>12</inf>F<inf>6</inf>N<inf>2</inf>O<inf>4</inf>)]·0.5C<inf>6</inf>H<inf>6</inf>O<inf>2</inf>, the CuII ion has a square-planar coordination geometry, being ligated by two N and two O atoms of the tetradentate open-chain Schiff base ligand 6,6′-{(1E,1′E)-[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis[2-(trifluoromethoxy)phenol]. The crystal packing is stabilized by intramolecular O-H..O and intermolecular C-H..F, C-H..O and C-H..π hydrogen bonds. In addition, weak π-π interactions form a three-dimensional structure. Hirshfeld surface analysis and two-dimensional fingerprint plots were performed and created to analyze the intermolecular interactions present in the crystal, indicating that the most important contributions for the crystal packing are from F..H/H..F (25.7%), H..H (23.5%) and C..H/H..C (12.6%) interactions. © 2019 International Union of Crystallography. All rights reserved. | en_US |
| dc.identifier.doi | 10.1107/S2056989019014294 | |
| dc.identifier.endpage | 1733 | en_US |
| dc.identifier.issn | 2056-9890 | |
| dc.identifier.pmid | 31709098 | |
| dc.identifier.scopus | 2-s2.0-85074787278 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 1729 | en_US |
| dc.identifier.uri | https://doi.org/10.1107/S2056989019014294 | |
| dc.identifier.volume | 75 | en_US |
| dc.identifier.wos | WOS:000495397100028 | |
| dc.language.iso | en | en_US |
| dc.publisher | International Union of Crystallography 5 Abbey Square Chester CH1 2HU | en_US |
| dc.relation.ispartof | ACTA Crystallographica Section E-Crystallographic Communications | en_US |
| dc.relation.journal | Acta Crystallographica Section E-Crystallographic Communications | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Copper (II) | en_US |
| dc.subject | Crystal Structure | en_US |
| dc.subject | Hirshfeld Surface | en_US |
| dc.subject | Salen-Type Schiff Base | en_US |
| dc.title | Crystal Structure and Hirshfeld Surface Analysis of 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(Azanylyl-Idene)]bis-(Methanylyl-Idene)}bis-[4-(Trifluoro-Methoxy)phenol]copper(II) Hydro-Quinone Hemisolvate | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |