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Trans-Bis(saccharinato)cadmium(II) Complexes with 2-Aminomethylpyridine and 2-Aminoethylpyridine - Synthesis, Crystal Structures, Spectral and Thermal Characterization of Trans- and Trans-[Cd(sac)2(aepy)2]

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dc.authorscopusid58717985000
dc.authorscopusid7005505517
dc.authorscopusid15033124400
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorCaglar, S.
dc.contributor.authorHarrison, W.T.A.
dc.date.accessioned2020-06-21T15:43:36Z
dc.date.available2020-06-21T15:43:36Z
dc.date.issued2004
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Caglar] Sema, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdomen_US
dc.description.abstractTwo trans-bis(saccharinato) (sac) complexes of cadmium(II) with 2-aminomethylpyridine (ampy) and 2-aminoethylpyridine (aepy) were synthesized and characterized by means of elemental analysis, FT-IR spectroscopy and thermal analysis. In addition, their solid-state structures were determined by single crystal X-ray diffraction studies. The [Cd(sac)<inf>2</inf>(ampy)<inf>2</inf>] (1) and [Cd(sac)<inf>2</inf>(aepy)] (2) complexes consist of neutral monomeric units and crystallize in the orthorhombic (Pbca) and monoclinic (P2 <inf>1</inf>/c) crystal systems, respectively. The cadmium(II) ions in 1 and 2 sit on inversion centres andexhibit distorted octahedral coordination by two sac anions and two aminopyridine ligands. The sac ligands in both complexes are N-coordinated and located in trans positions. while the ampy and aepy ligands act as a bidentate ligand forming two symmetrically chelate rings around cadmium(II). IR spectra and thermal decompositions of the complexes are also discussed.en_US
dc.identifier.doi10.1002/zaac.200400114
dc.identifier.endpage1130en_US
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-4644234546
dc.identifier.scopusqualityQ3
dc.identifier.startpage1126en_US
dc.identifier.urihttps://doi.org/10.1002/zaac.200400114
dc.identifier.volume630en_US
dc.identifier.wosWOS:000222967800029
dc.language.isoenen_US
dc.publisherWiley-VCH Verlag GmbHen_US
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen_US
dc.relation.journalZeitschrift Fur Anorganische Und Allgemeine Chemieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Aminoethylpyridineen_US
dc.subject2-Aminomethylpyridineen_US
dc.subjectCadmiumen_US
dc.subjectSaccharinen_US
dc.titleTrans-Bis(saccharinato)cadmium(II) Complexes with 2-Aminomethylpyridine and 2-Aminoethylpyridine - Synthesis, Crystal Structures, Spectral and Thermal Characterization of Trans- and Trans-[Cd(sac)2(aepy)2]en_US
dc.title.alternativeCd(Sac)2en_US
dc.typeArticleen_US
dspace.entity.typePublication

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