Publication: Synthesis and Crystal Structure of Trans-Bis(Acesulfamato Tetraaquazinc(II)
| dc.authorscopusid | 8361848500 | |
| dc.authorscopusid | 55159584400 | |
| dc.authorscopusid | 36039473500 | |
| dc.contributor.author | Sahin, O. | |
| dc.contributor.author | İçbudak, H. | |
| dc.contributor.author | Büyükgüngör, O. | |
| dc.date.accessioned | 2020-06-21T09:27:31Z | |
| dc.date.available | 2020-06-21T09:27:31Z | |
| dc.date.issued | 2010 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Sahin] Onur, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Íçbudak] Hasan, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey | en_US |
| dc.description.abstract | The title compound, trans-bis(acesulfamato-O)tetraaquazinc(II) (I, C <inf>8</inf>H<inf>16</inf>N<inf>2</inf>O<inf>12</inf>S<inf>2</inf>Zn), crystallizes in the triclinic system, space group P1̄ with a = 5.1638(5), b = 8.5338(9), c = 9.9583(9) Å, α = 74.325(8), β = 81.112(7), γ = 75.800(8)°, V = 407.77(7) Å3, Z = 1, F(000) = 236, R<inf>int</inf> = 0.085, T = 296 K, the final R = 0.029 and wR = 0.078 for 1832 observed reflections with I > 2σ(I). The ZnII centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is defined by two carbonyl O atoms of two monodentate trans-oriented acesulfamato ligands and two trans-aqua ligands. The axial positions in the octahedron are occupied by two trans-aqua ligands. Intermolecular O-H⋯O hydrogen bonds produce R2<inf>2</inf>(8) and R2 <inf>2</inf>(16) rings, which lead to two-dimensional polymeric chains. | en_US |
| dc.identifier.endpage | 1050 | en_US |
| dc.identifier.issn | 0254-5861 | |
| dc.identifier.issue | 7 | en_US |
| dc.identifier.scopus | 2-s2.0-77954904148 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 1047 | en_US |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/4081 | |
| dc.identifier.volume | 29 | en_US |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.relation.ispartof | Chinese Journal of Structural Chemistry | en_US |
| dc.relation.journal | Jiegou Huaxue | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Complex | en_US |
| dc.subject | Crystal Structure | en_US |
| dc.subject | Hydrogen Bonds | en_US |
| dc.subject | Octahedral | en_US |
| dc.subject | Zinc(II) | en_US |
| dc.title | Synthesis and Crystal Structure of Trans-Bis(Acesulfamato Tetraaquazinc(II) | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |