Publication:
Two Novel Unsymmetrical Ferrocene Based Azines and Their Complexing Abilities Towards Cu(II): Spectroscopy, Crystal Structure, Electrochemistry and DFT Calculations

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dc.authorscopusid36095757100
dc.authorscopusid56497950600
dc.authorscopusid6602376941
dc.authorscopusid35567972100
dc.authorscopusid7004106981
dc.contributor.authorEmirik, M.
dc.contributor.authorKaraoglu, K.
dc.contributor.authorSerbest, K.
dc.contributor.authorÇoruh, U.
dc.contributor.authorVázquez Lõpez, E.M.
dc.date.accessioned2020-06-21T09:42:59Z
dc.date.available2020-06-21T09:42:59Z
dc.date.issued2015
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Emirik] Mustafa, Department of Chemistry, Recep Tayyip Erdogon University, Rize, Turkey; [Karaoglu] Kaan, Department of Chemistry, Recep Tayyip Erdogon University, Rize, Turkey; [Serbest] Kerim, Department of Chemistry, Recep Tayyip Erdogon University, Rize, Turkey; [Çoruh] Ufuk, Department of Computer Education and Instructional Technology, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Vázquez Lõpez] Ezequiel M., Department of Inorganic Chemistry, Universidade de Vigo, Vigo, Galicia, Spainen_US
dc.description.abstractTwo new ferrocenyl-substituted unsymmetric azine ligands and their Cu(II) complexes were prepared. The redox active ferrocene-based azine ligands 1 and 2 were obtained by the condensation of 1-[(E)-hydrazinylidenemethyl]naphthalen-2-ol and 2-[(E)-hydrazinylidenemethyl]-4-nitrophenol with ferrocenecarboxaldehyde, respectively. The structures of the ligands and their Cu(II) complexes were characterized by IR, UV-Vis, NMR, X-ray, magnetic measurements and TG techniques. The 2-[(E)-hydraz-inylidenemethyl]-4-nitrophenol derivative azine ligand (2) was found to be rearranged by the Cu(II) ion without water or acid/base catalyst. The redox behaviors of the ferrocene derivative compounds were investigated by cyclic voltammetry. Structural parameters and spectroscopic properties of the azine ligands (1 and 2) and the Cu(II) complex (1a) were calculated using DFT and TD-DFT/CPCM methods and the results were compared with the experimental data. © 2015 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.poly.2014.12.044
dc.identifier.endpage189en_US
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84921921032
dc.identifier.scopusqualityQ2
dc.identifier.startpage182en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2014.12.044
dc.identifier.urihttps://hdl.handle.net/20.500.12712/5231
dc.identifier.volume88en_US
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPOLYHEDRONen_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAzineen_US
dc.subjectCrystal Structureen_US
dc.subjectElectrochemical Propertiesen_US
dc.subjectFerroceneen_US
dc.subjectTD-DFTen_US
dc.titleTwo Novel Unsymmetrical Ferrocene Based Azines and Their Complexing Abilities Towards Cu(II): Spectroscopy, Crystal Structure, Electrochemistry and DFT Calculationsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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