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Two-Dimensional Heteropolynuclear Zn(II) and Cd(II)-Tetracyanopalladate(II) Complexes with the 1-Ethylimidazole Ligand Exhibiting C-H⋯Pd Interactions

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dc.authorscopusid55239854400
dc.authorscopusid49863490200
dc.authorscopusid16403949600
dc.authorscopusid36039473500
dc.contributor.authorÇetinkaya, F.
dc.contributor.authorKürkçüoǧlu, G.S.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:05:34Z
dc.date.available2020-06-21T14:05:34Z
dc.date.issued2013
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çetinkaya] Fulya, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractThe cyano-bridged heteronuclear complexes [Zn(etim)<inf>2</inf>Pd(μ-CN) <inf>4</inf>]<inf>n</inf> (1) and [Cd(etim)<inf>2</inf>Pd(μ-CN) <inf>4</inf>]<inf>n</inf> (2) (etim = 1-ethylimidazole), have been synthesized and characterized by FT-IR, Raman spectroscopy, thermal and elemental analyses. The crystal structures of the complexes have been determined by X-ray single crystal diffraction. In the complexes, the Pd(II) ion is coordinated by four cyano ligands, forming a square-planar geometry, and the Zn(II) or Cd(II) ions are coordinated by six N atoms from four bridging cyano ligands and two etim ligands in a distorted octahedral geometry. The most important features of the complexes are the presence of C-H···Pd hydrogen-bonding interactions between the Pd(II) ion and the hydrogen atoms of the etim ligand. © 2013 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.poly.2013.02.047
dc.identifier.endpage17en_US
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84876565055
dc.identifier.scopusqualityQ2
dc.identifier.startpage10en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2013.02.047
dc.identifier.volume55en_US
dc.identifier.wosWOS:000319245700002
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1-Ethylimidazole Complexesen_US
dc.subjectHeterometallic Complexesen_US
dc.subjectIntermolecular C-H···Pd Interactionsen_US
dc.subjectTetracyanopalladate(II) Complexesen_US
dc.subjectVibrational Spectraen_US
dc.titleTwo-Dimensional Heteropolynuclear Zn(II) and Cd(II)-Tetracyanopalladate(II) Complexes with the 1-Ethylimidazole Ligand Exhibiting C-H⋯Pd Interactionsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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