Publication:
Uncommon Coordination Modes of 4-Methylimidazole in [Zn(4-Meim)2(5-Meim)2]sq·3H2O

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dc.authorscopusid16403949600
dc.authorscopusid25640606900
dc.authorscopusid36039473500
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorErer, H.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:06:13Z
dc.date.available2020-06-21T15:06:13Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Erer] Hakan, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractA novel Zn(II) complex, [Zn(4-Meim)<inf>2</inf>(5-Meim)<inf>2</inf>]sq·3H<inf>2</inf>O (1), (H<inf>2</inf>sq = squaric acid, 4-Meim = 4-methylimidazole and 5-Meim = 5-methylimidazole) has been synthesized and characterized by elemental, spectral (IR), thermal analyses and single crystal X-ray diffraction techniques. The Zn(II) ion center accommodates two binding types of the 4(5)-Meim ligand in same coordination sphere, which is a very unique example of the linkage isomers. The sq counterion interacts each other though water bridges by strong hydrogen bonds forming a zig-zag chain along the b-axis and generate R<inf>4</inf>4 (14) motif. The adjacent chains are connected by the water molecule forming a R<inf>8</inf>8 (22) aperture. © 2009 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.inoche.2009.05.034
dc.identifier.endpage727en_US
dc.identifier.issn1387-7003
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-67651225119
dc.identifier.scopusqualityQ2
dc.identifier.startpage724en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2009.05.034
dc.identifier.volume12en_US
dc.identifier.wosWOS:000269400000007
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.journalInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject4-Methylimidazole Complexen_US
dc.subject5-Methylimidazole Complexen_US
dc.subjectLinkage Isomerismen_US
dc.subjectSquarate Complexen_US
dc.subjectZinc(II) Complexen_US
dc.titleUncommon Coordination Modes of 4-Methylimidazole in [Zn(4-Meim)2(5-Meim)2]sq·3H2Oen_US
dc.typeArticleen_US
dspace.entity.typePublication

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