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Synthesis and Characterization of Ru(II)-NSHC Catalysts Bearing Thiamine Analogs in Water-Solvent Transfer Hydrogenation Catalysis

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dc.authorscopusid16052784700
dc.authorscopusid59407586400
dc.authorscopusid59132916000
dc.authorscopusid59407487600
dc.authorscopusid8398877200
dc.authorscopusid7006471258
dc.authorwosidKilinçarslan, Rafet/D-8120-2015
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.authorwosidTuncer, Hayriye/Aax-6639-2021
dc.authorwosidKılınçarslan, Rafet/D-8120-2015
dc.authorwosidTuncer, Hayriye/Aax-6639-2021
dc.contributor.authorKilincarslan, Rafet
dc.contributor.authorMenderes, Melek
dc.contributor.authorTuncer, Hayriye
dc.contributor.authorOzdemir, Sedef
dc.contributor.authorOzdemir, Namik
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorIDKilinçarslan, Rafet/0000-0001-6982-9536
dc.contributor.authorIDÖzdemir, Namık/0000-0003-3371-9874
dc.contributor.authorIDTuncer, Hayriye/0000-0002-4261-5965
dc.date.accessioned2025-12-11T01:30:22Z
dc.date.issued2025
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kilincarslan, Rafet; Menderes, Melek; Tuncer, Hayriye; Ozdemir, Sedef] Pamukkale Univ, Fac Sci, Dept Chem, Kinikli Campus, TR-20017 Denizli, Turkiye; [Ozdemir, Namik] Ondokuz Mayis Univ, Fac Sci, Dept Pyhs, TR-55139 Samsun, Turkiye; [Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Izmir, Turkiyeen_US
dc.descriptionKilinçarslan, Rafet/0000-0001-6982-9536; Özdemir, Namık/0000-0003-3371-9874; Tuncer, Hayriye/0000-0002-4261-5965en_US
dc.description.abstractThiamine analogues with 3-methyl and 4-(2-hydroxyethyl) substituents on the backbone of thiazole ring, were used to synthesize monodentate Ru(II)-thiazolylidene complexes in a single step via transmetalation under mild conditions. These novel complexes catalyze the conversion of ketones and aldehydes to alcohols by transfer hydrogenation in a 5 : 2 HCO2H/NEt3 buffer in water. However, their efficiency was found to be much lower than the thiamine-derived bidentate Ru(II) complexes, which strongly indicates that the 'N-H' plays a crucial role in the reaction.en_US
dc.description.sponsorshipPamukkale University Scientific Research Projects Commission; Scientific and Technological Research Application and Research Center of Sinop University; [2023FEBE011]en_US
dc.description.sponsorshipFinancial support for this work was provided by the Pamukkale University Scientific Research Projects Commission (Project No: 2023FEBE011). The authors acknowledge to Scientific and Technological Research Application and Research Center of Sinop University for the X-ray data collections.en_US
dc.description.woscitationindexScience Citation Index Expanded - Index Chemicus
dc.identifier.doi10.1002/ejic.202400621
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85208816428
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1002/ejic.202400621
dc.identifier.urihttps://hdl.handle.net/20.500.12712/44159
dc.identifier.volume28en_US
dc.identifier.wosWOS:001397174800003
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherWiley-VCH Verlag GmbHen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectThiamineen_US
dc.subjectThiazol-2-Ylideneen_US
dc.subjectRu(II)-NSHCen_US
dc.subjectN,S-Heterocyclic Carbeneen_US
dc.subjectTransfer Hydrogenationen_US
dc.titleSynthesis and Characterization of Ru(II)-NSHC Catalysts Bearing Thiamine Analogs in Water-Solvent Transfer Hydrogenation Catalysisen_US
dc.typeArticleen_US
dspace.entity.typePublication

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