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Investigation of the Acid-Catalyzed Hydrolysis and Reaction Mechanisms of N,N′-Diarylsulfamides Using Various Criteria

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dc.authorscopusid7801686683
dc.authorscopusid42461181600
dc.authorscopusid6701793097
dc.contributor.authorBekdemir, Y.
dc.contributor.authorGediz Erturk, A.G.
dc.contributor.authorKütük, H.
dc.date.accessioned2020-06-21T13:58:00Z
dc.date.available2020-06-21T13:58:00Z
dc.date.issued2014
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Bekdemir] Yunus, Canik Başari Üniversitesi, Samsun, Turkey; [Gediz Erturk] Aliye, Department of Chemistry, Ordu Üniversitesi, Ordu, Turkey; [Kütük] Halil, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe mechanism of acid-catalyzed hydrolysis of a series of p-substituted N,N′-diarylsulfamides was investigated in aqueous mineral acid solutions. Rate profiles, reaction activation parameters, catalytic order of strong acids, solvent isotope effects, and analysis of the kinetic data by the excess acidity method suggest a change in the mechanism from A2 to A1. While the hydrolysis proceeds with an A2 mechanism in low acidity regions, an A1 mechanism takes place in high acid concentrations. Copyright © 2013 John Wiley & Sons, Ltd.en_US
dc.identifier.doi10.1002/poc.3242
dc.identifier.endpage98en_US
dc.identifier.issn0894-3230
dc.identifier.issn1099-1395
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-84892783584
dc.identifier.scopusqualityQ3
dc.identifier.startpage94en_US
dc.identifier.urihttps://doi.org/10.1002/poc.3242
dc.identifier.volume27en_US
dc.identifier.wosWOS:000329791800003
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofJournal of Physical Organic Chemistryen_US
dc.relation.journalJournal of Physical Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcid Catalysisen_US
dc.subjectDiarylsulfamidesen_US
dc.subjectExcess Acidityen_US
dc.subjectHydrolysisen_US
dc.subjectMechanismen_US
dc.titleInvestigation of the Acid-Catalyzed Hydrolysis and Reaction Mechanisms of N,N′-Diarylsulfamides Using Various Criteriaen_US
dc.typeArticleen_US
dspace.entity.typePublication

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