Publication:
2-[(E)-(4-Methyl-Phen-yl)Imino-Meth-yl]-6-(Morpholin-4-Ylmeth-yl)Phenol

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Abstract

In the title compound, C<inf>19</inf>H<inf>22</inf>N<inf>2</inf>O <inf>2</inf>, the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters QT, θ and φ of 0.5642 (18) Å, 177.32 (17) and φ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8) ° with each other. An intramolecular O - H⋯N hydrogen bond helps to stabilize the molecular conformation. Aromatic C - H⋯π interactions and π- π stacking interactions [centroid-centroid distance = 3.6155 (15) Å] between the benzene rings contribute to the stabilization of the crystal structure.

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Source

Acta Crystallographica Section E: Structure Reports Online

Volume

67

Issue

1

Start Page

o147

End Page

o148

Endorsement

Review

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