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Coupling of Pentacarbonyl[(cyclopropyl)methoxymethylene]molybdenum Complex With Ferrocenyl Alkynes: Synthesis of Ferrocenyl-Substituted Cycloheptadienones and Cycloheptenediones

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dc.authorscopusid6603747040
dc.authorscopusid56898858600
dc.authorscopusid8328133400
dc.authorscopusid36039473500
dc.contributor.authorZora, M.
dc.contributor.authorAçikgöz, C.
dc.contributor.authorOdaba̧soǧlu, M.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:23:53Z
dc.date.available2020-06-21T15:23:53Z
dc.date.issued2007
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Zora] Metin, Department of Chemistry, Middle East Technical University (METU), Ankara, Ankara, Turkey; [Açikgöz] Canet, Department of Chemistry, Middle East Technical University (METU), Ankara, Ankara, Turkey; [Odaba̧soǧlu] Mustafà, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractPentacarbonyl[(cyclopropyl)methoxymethylene]molybdenum complex reacts with ferrocenyl alkynes to afford ferrocenyl-substituted 2,4-cycloheptadienones as major products, accompanied by varying amounts of 2-cycloheptene-1,4-diones and/or 2-cyclobutenones. 2-Cycloheptene-1,4-diones are secondary reaction products and result from initially formed 2,4-cycloheptadienones via hydrolysis. In one reaction, a hydroxy-substituted 2,4-cycloheptadienone derivative was isolated, which was not observed previously from similar reactions. © 2006 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2006.12.008
dc.identifier.endpage1578en_US
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-33846844830
dc.identifier.startpage1571en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2006.12.008
dc.identifier.volume692en_US
dc.identifier.wosWOS:000246468400016
dc.language.isoenen_US
dc.publisherElsevier Science SAen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.journalJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCarbocyclic Seven-Membered Ringsen_US
dc.subjectCouplingen_US
dc.subjectCyclobutenonesen_US
dc.subjectCycloheptadienonesen_US
dc.subjectCycloheptenedionesen_US
dc.subjectFerroceneen_US
dc.subjectFerrocenyl Alkynesen_US
dc.subjectFischer Metal Carbeneen_US
dc.subjectMolybdenum Carbene Complexen_US
dc.titleCoupling of Pentacarbonyl[(cyclopropyl)methoxymethylene]molybdenum Complex With Ferrocenyl Alkynes: Synthesis of Ferrocenyl-Substituted Cycloheptadienones and Cycloheptenedionesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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