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Spectroscopic Studies on Thermally Induced Intramolecular Electron Transfer Reaction of Tetraaquabis(Saccharinato)iron Dihydrate in the Solid State

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dc.authorscopusid58717985000
dc.contributor.authorYilmaz, V.T.
dc.date.accessioned2025-12-11T02:00:22Z
dc.date.issued1999
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe thermally induced electron transfer reaction of the saccharin complex with iron(II) in the solid state was investigated by using DTA, DSC, TG, IR, EPR, Mössbauer spectroscopy, magnetic and XRPD measurements. Experimental data suggest that an intramolecular electron transfer reaction occurs during dehydration of the complex. The electron transfer reaction leads to dimerization of the dehydrated complex by the formation of hydroxo bridges. The probable mechanistic pathway of the reaction is also proposed.en_US
dc.identifier.doi10.1080/00945719909349475
dc.identifier.endpage633en_US
dc.identifier.issn0094-5714
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-0033410674
dc.identifier.startpage621en_US
dc.identifier.urihttps://doi.org/10.1080/00945719909349475
dc.identifier.urihttps://hdl.handle.net/20.500.12712/47545
dc.identifier.volume29en_US
dc.institutionauthorYilmaz, V.T.
dc.language.isoenen_US
dc.publisherMarcel Dekker Inc.en_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic and Metal-Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSpectroscopic Studies on Thermally Induced Intramolecular Electron Transfer Reaction of Tetraaquabis(Saccharinato)iron Dihydrate in the Solid Stateen_US
dc.typeArticleen_US
dspace.entity.typePublication

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