Publication:
One-Dimensional Heteropolynuclear Tetracyanopalladate(II) Complexes: Syntheses, Crystal Structures, Thermal Analyses and Spectroscopic Investigations

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dc.authorscopusid36905553700
dc.authorscopusid49863490200
dc.authorscopusid16403949600
dc.authorscopusid36039473500
dc.contributor.authorAksel, M.
dc.contributor.authorKürkçüoǧlu, G.S.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T13:57:53Z
dc.date.available2020-06-21T13:57:53Z
dc.date.issued2014
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Aksel] Mehran, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractThree new complexes, [Ni(deten)<inf>2</inf>Pd(μ-CN)<inf>2</inf>(CN) <inf>2</inf>]<inf>n</inf> (1), [Zn(deten)<inf>2</inf>Pd(μ-CN) <inf>2</inf>(CN)<inf>2</inf>]<inf>n</inf> (2) and [Cd(deten)<inf>2</inf>Pd(μ- CN)<inf>2</inf>(CN)<inf>2</inf>]<inf>n</inf> (3) (deten = N,N- diethylethylenediamine), have been synthesized and characterized by elemental, spectral (FT-IR and Raman) and thermal analysis techniques. The crystal structures of the complexes 2 and 3 have been determined by X-ray single crystal diffraction. The crystallographic analysis reveals that they crystallize in the monoclinic system, space group P2<inf>1</inf>/c. The Pd(II) atom is coordinated by four cyano groups. The M(II) atom is also surrounded by the two symmetry related deten ligands and the two symmetry related N atom of cyano groups. A possible decomposition of the complexes was investigated in the temperature range 30-700 C in static air. © 2013 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2013.11.006
dc.identifier.endpage107en_US
dc.identifier.issn0022-2860
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84890041992
dc.identifier.scopusqualityQ1
dc.identifier.startpage101en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2013.11.006
dc.identifier.volume1059en_US
dc.identifier.wosWOS:000331157500016
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.journalJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyano Bridged Complexesen_US
dc.subjectHeterometallic Complexesen_US
dc.subjectN,N-Diethylethylenediamine Complexesen_US
dc.subjectTetracyanopalladate(II) Complexesen_US
dc.titleOne-Dimensional Heteropolynuclear Tetracyanopalladate(II) Complexes: Syntheses, Crystal Structures, Thermal Analyses and Spectroscopic Investigationsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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